Growth kinetics of racemic heptahelicene-2-carboxylic acid nanowires on calcite (104)

Einax M, Richter T, Nimmrich M, Rahe P, Stara IG, Stary I, Kühnle A, Maass P (2016)
Journal of Chemical Physics 145: 134702.

Zeitschriftenaufsatz | Veröffentlicht | Englisch
 
Download
OA 9.61 MB
Autor*in
Einax, Mario; Richter, Tobias; Nimmrich, Markus; Rahe, Philipp; Stara, Irena G.; Stary, Ivo; Kühnle, AngelikaUniBi; Maass, Philipp
Abstract / Bemerkung
Molecular self-assembly of racemic heptahelicene-2-carboxylic acid on a dielectric substrate at room temperature can be used to generate wire-like organic nanostructures consisting of single and double molecular rows. By means of non-contact atomic force microscopy, we investigate the growth of the wire-like pattern after deposition by experimental and theoretical means. From analyzing the time dependence of the mean row length, two distinct regimes were found. At the early post-deposition stage, the mean length grows in time. Subsequently, a crossover to a second regime is observed, where the mean row length remains nearly constant. We explain these findings by a mean-field rate equation approach providing a comprehensive picture of the growth kinetics. As a result, we demonstrate that the crossover between the two distinct regimes is accomplished by vanishing of the homochiral single rows. At later stages only heterochiral double row structures remain. Published by AIP Publishing.
Erscheinungsjahr
2016
Zeitschriftentitel
Journal of Chemical Physics
Band
145
Seite(n)
134702
ISSN
0021-9606
eISSN
1089-7690
Page URI
https://pub.uni-bielefeld.de/record/2913781

Zitieren

Einax M, Richter T, Nimmrich M, et al. Growth kinetics of racemic heptahelicene-2-carboxylic acid nanowires on calcite (104). Journal of Chemical Physics. 2016;145:134702.
Einax, M., Richter, T., Nimmrich, M., Rahe, P., Stara, I. G., Stary, I., Kühnle, A., et al. (2016). Growth kinetics of racemic heptahelicene-2-carboxylic acid nanowires on calcite (104). Journal of Chemical Physics, 145, 134702. https://doi.org/10.1063/1.4963724
Einax, Mario, Richter, Tobias, Nimmrich, Markus, Rahe, Philipp, Stara, Irena G., Stary, Ivo, Kühnle, Angelika, and Maass, Philipp. 2016. “Growth kinetics of racemic heptahelicene-2-carboxylic acid nanowires on calcite (104)”. Journal of Chemical Physics 145: 134702.
Einax, M., Richter, T., Nimmrich, M., Rahe, P., Stara, I. G., Stary, I., Kühnle, A., and Maass, P. (2016). Growth kinetics of racemic heptahelicene-2-carboxylic acid nanowires on calcite (104). Journal of Chemical Physics 145, 134702.
Einax, M., et al., 2016. Growth kinetics of racemic heptahelicene-2-carboxylic acid nanowires on calcite (104). Journal of Chemical Physics, 145, p 134702.
M. Einax, et al., “Growth kinetics of racemic heptahelicene-2-carboxylic acid nanowires on calcite (104)”, Journal of Chemical Physics, vol. 145, 2016, pp. 134702.
Einax, M., Richter, T., Nimmrich, M., Rahe, P., Stara, I.G., Stary, I., Kühnle, A., Maass, P.: Growth kinetics of racemic heptahelicene-2-carboxylic acid nanowires on calcite (104). Journal of Chemical Physics. 145, 134702 (2016).
Einax, Mario, Richter, Tobias, Nimmrich, Markus, Rahe, Philipp, Stara, Irena G., Stary, Ivo, Kühnle, Angelika, and Maass, Philipp. “Growth kinetics of racemic heptahelicene-2-carboxylic acid nanowires on calcite (104)”. Journal of Chemical Physics 145 (2016): 134702.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Creative Commons Namensnennung 4.0 International Public License (CC-BY 4.0):
Volltext(e)
Access Level
OA Open Access
Zuletzt Hochgeladen
2019-09-06T09:18:51Z
MD5 Prüfsumme
0d73e147c90591ad465f86b303ed48ef


1 Zitation in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Self-assembly of 1,3,5-benzenetribenzoic acid on Ag and Cu at the liquid/solid interface.
Aitchison H, Lu H, Ortiz de la Morena R, Cebula I, Zharnikov M, Buck M., Phys Chem Chem Phys 20(4), 2018
PMID: 29322147

37 References

Daten bereitgestellt von Europe PubMed Central.

Electron transport in molecular wire junctions.
Nitzan A, Ratner MA., Science 300(5624), 2003
PMID: 12775831

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0
Single-electron transistor of a single organic molecule with access to several redox states.
Kubatkin S, Danilov A, Hjort M, Cornil J, Bredas JL, Stuhr-Hansen N, Hedegard P, Bjornholm T., Nature 425(6959), 2003
PMID: 14562098

AUTHOR UNKNOWN, 0
Tuning molecular self-assembly on bulk insulator surfaces by anchoring of the organic building blocks.
Rahe P, Kittelmann M, Neff JL, Nimmrich M, Reichling M, Maass P, Kuhnle A., Adv. Mater. Weinheim 25(29), 2013
PMID: 23907708

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0
Concept for support and cleavage of brittle crystals.
Troger L, Schutte J, Ostendorf F, Kuhnle A, Reichling M., Rev Sci Instrum 80(6), 2009
PMID: 19566206
NC-AFM contrast formation on the calcite (1014) surface.
Rahe P, Schutte J, Kuhnle A., J Phys Condens Matter 24(8), 2012
PMID: 22310301

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0
Initial stages of Cu epitaxy on Ni(100): Postnucleation and a well-defined transition in critical island size.
Muller B, Nedelmann L, Fischer B, Brune H, Kern K., Phys. Rev., B Condens. Matter 54(24), 1996
PMID: 9985917

AUTHOR UNKNOWN, 0
Characterization of step-edge barriers in organic thin-film growth.
Hlawacek G, Puschnig P, Frank P, Winkler A, Ambrosch-Draxl C, Teichert C., Science 321(5885), 2008
PMID: 18599783

AUTHOR UNKNOWN, 0
Second-layer induced island morphologies in thin-film growth of fullerenes.
Korner M, Loske F, Einax M, Kuhnle A, Reichling M, Maass P., Phys. Rev. Lett. 107(1), 2011
PMID: 21797552
Novel growth mechanism of epitaxial graphene on metals.
Zangwill A, Vvedensky DD., Nano Lett. 11(5), 2011
PMID: 21495700
Scaling of island densities in submonolayer growth of binary alloys.
Einax M, Ziehm S, Dieterich W, Maass P., Phys. Rev. Lett. 99(1), 2007
PMID: 17678169

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0
Dynamics of irreversible island growth during submonolayer epitaxy.
Bales GS, Chrzan DC., Phys. Rev., B Condens. Matter 50(9), 1994
PMID: 9976977

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 0
Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®
Quellen

PMID: 27782411
PubMed | Europe PMC

Suchen in

Google Scholar