Probing the magnetic moments of [MnIII6CrIII]3+single-moleculemagnets : A cross comparison of XMCD and spin-resolvedelectron spectroscopy
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Single-molecule magnets (SMM) of the [MnIII6CrIII]3+ structural type prepared on Si and gold-coated glass substrates have been investigated by spin-resolved electron spectroscopy (SPES) and X-ray magnetic circular dichroism (XMCD) at the Mn L3,2 edge and in addition by XMCD at the Cr L3,2 edge using synchrotron radiation. Differences between the two methods are discussed. Despite its severe limitations for 3d transition metals, a spin sum rule evaluation is nevertheless performed for the MnIII centres in the [MnIII6CrIII]3+ SMM to provide a simple means of comparing XMCD and spin-resolved electron spectroscopy results.
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HELMSTEDT, Andreas, Niklas DOHMEIER, Norbert MÜLLER, Aaron GRYZIA, Armin BRECHLING, Ulrich HEINZMANN, Veronika HOEKE, Erich KRICKEMEYER, Thorsten GLASER, Philipp LEICHT, Mikhail FONIN, Thomas TIETZE, Loïc JOLY, Karsten KUEPPER, 2015. Probing the magnetic moments of [MnIII6CrIII]3+single-moleculemagnets : A cross comparison of XMCD and spin-resolvedelectron spectroscopy. In: Journal of Electron Spectroscopy and Related Phenomena. 2015, 198, pp. 12-19. ISSN 0368-2048. eISSN 1873-2526. Available under: doi: 10.1016/j.elspec.2014.11.005BibTex
@article{Helmstedt2015Probi-30829, year={2015}, doi={10.1016/j.elspec.2014.11.005}, title={Probing the magnetic moments of [Mn<sup>III</sup><sub>6</sub>Cr<sup>III</sup>]<sup>3+</sup>single-moleculemagnets : A cross comparison of XMCD and spin-resolvedelectron spectroscopy}, volume={198}, issn={0368-2048}, journal={Journal of Electron Spectroscopy and Related Phenomena}, pages={12--19}, author={Helmstedt, Andreas and Dohmeier, Niklas and Müller, Norbert and Gryzia, Aaron and Brechling, Armin and Heinzmann, Ulrich and Hoeke, Veronika and Krickemeyer, Erich and Glaser, Thorsten and Leicht, Philipp and Fonin, Mikhail and Tietze, Thomas and Joly, Loïc and Kuepper, Karsten} }
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