Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?

Nitsch, Jörn; Lacemon, Frederick; Lorbach, Andreas; Eichhorn, Antonius; Cisnetti, Federico; Steffen, Andreas

Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?

Dateien

Nitsch_0-326695.pdfGröße: 2.01 MBDownloads: 519

Datum

2016

Autor:innen

Nitsch, Jörn

Lacemon, Frederick

Lorbach, Andreas

Eichhorn, Antonius

Cisnetti, Federico

Steffen, Andreas

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Chemical Communications : ChemComm. 2016, 52(14), pp. 2932-2935. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C5CC09659F

Zusammenfassung

This case study on a series of monomeric, dimeric and polymeric Cu^I chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T₁ ↔ S₁ and T₁ → S₀, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T₁ emitters.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

NITSCH, Jörn, Frederick LACEMON, Andreas LORBACH, Antonius EICHHORN, Federico CISNETTI, Andreas STEFFEN, 2016. Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?. In: Chemical Communications : ChemComm. 2016, 52(14), pp. 2932-2935. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C5CC09659F

BibTex

@article{Nitsch2016Cupro-33981,
  year={2016},
  doi={10.1039/C5CC09659F},
  title={Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?},
  number={14},
  volume={52},
  issn={1359-7345},
  journal={Chemical Communications : ChemComm},
  pages={2932--2935},
  author={Nitsch, Jörn and Lacemon, Frederick and Lorbach, Andreas and Eichhorn, Antonius and Cisnetti, Federico and Steffen, Andreas}
}

RDF

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/33981">
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/33981/1/Nitsch_0-326695.pdf"/>
    <dc:creator>Lacemon, Frederick</dc:creator>
    <dcterms:issued>2016</dcterms:issued>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:language>eng</dc:language>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dcterms:abstract xml:lang="eng">This case study on a series of monomeric, dimeric and polymeric Cu&lt;sup&gt;I&lt;/sup&gt; chlorido NHC–picolyl complexes shows that cuprophilic interactions can ensure strong spin–orbit coupling for fast (reverse)intersystem-crossing T&lt;sub&gt;1&lt;/sub&gt; ↔ S&lt;sub&gt;1&lt;/sub&gt; and T&lt;sub&gt;1&lt;/sub&gt; → S&lt;sub&gt;0&lt;/sub&gt;, and therefore can serve as a design motif for the construction of highly efficient CuI-based TADF or T&lt;sub&gt;1&lt;/sub&gt; emitters.</dcterms:abstract>
    <dc:contributor>Eichhorn, Antonius</dc:contributor>
    <dcterms:title>Cuprophilic interactions in highly luminescent dicopper (I)–NHC–picolyl complexes – fast phosphorescence or TADF?</dcterms:title>
    <dc:creator>Nitsch, Jörn</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-05-18T09:20:05Z</dc:date>
    <dc:contributor>Lacemon, Frederick</dc:contributor>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/33981/1/Nitsch_0-326695.pdf"/>
    <dc:contributor>Lorbach, Andreas</dc:contributor>
    <dc:creator>Lorbach, Andreas</dc:creator>
    <dc:contributor>Nitsch, Jörn</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-05-18T09:20:05Z</dcterms:available>
    <dc:creator>Steffen, Andreas</dc:creator>
    <dc:creator>Eichhorn, Antonius</dc:creator>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/33981"/>
    <dc:contributor>Steffen, Andreas</dc:contributor>
    <dc:rights>terms-of-use</dc:rights>
    <dc:contributor>Cisnetti, Federico</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:creator>Cisnetti, Federico</dc:creator>
  </rdf:Description>
</rdf:RDF>

Universitätsbibliographie

Ja