@article{Zhang2016Photo-35386,
  year={2016},
  doi={10.1039/C6CP03243E},
  title={Photoelectron spectroscopic and computational study of the PtMgH<sub>3,5</sub>− cluster anions},
  number={28},
  volume={18},
  issn={1463-9076},
  journal={Physical Chemistry Chemical Physics},
  pages={19345--19349},
  author={Zhang, Xinxing and Ganteför, Gerd and Alexandrova, Anastassia N. and Bowen, Kit}
}

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    <dcterms:title>Photoelectron spectroscopic and computational study of the PtMgH&lt;sub&gt;3,5&lt;/sub&gt;− cluster anions</dcterms:title>
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    <dc:contributor>Bowen, Kit</dc:contributor>
    <dc:contributor>Zhang, Xinxing</dc:contributor>
    <dc:contributor>Ganteför, Gerd</dc:contributor>
    <dc:language>eng</dc:language>
    <dcterms:abstract xml:lang="eng">The two cluster anions, PtMgH&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;−&lt;/sup&gt; and PtMgH&lt;sub&gt;5&lt;/sub&gt;&lt;sup&gt;−&lt;/sup&gt;, were studied by photoelectron spectroscopy and theoretical calculations. Experimentally-determined electron affinity (EA) and vertical detachment energy (VDE) values were compared with those predicted by our computations; excellent agreement was found. The calculated structures of PtMgH&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;−&lt;/sup&gt; and PtMgH&lt;sub&gt;3&lt;/sub&gt; both exhibit η&lt;sub&gt;2&lt;/sub&gt;-bonded H&lt;sub&gt;2&lt;/sub&gt; moieties. Activation of these H&lt;sub&gt;2&lt;/sub&gt; moieties is implied by the elongation of their bond lengths relative to the bond length of free H&lt;sub&gt;2&lt;/sub&gt;. The calculated structures of PtMgH&lt;sub&gt;5&lt;/sub&gt;&lt;sup&gt;−&lt;/sup&gt; and PtMgH&lt;sub&gt;5&lt;/sub&gt; both exhibit all-hydrogen, five-member, σ-aromatic rings. These attributes are responsible for this anion's special stability.</dcterms:abstract>
    <dc:contributor>Alexandrova, Anastassia N.</dc:contributor>
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    <dc:creator>Ganteför, Gerd</dc:creator>
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    <dc:creator>Bowen, Kit</dc:creator>
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    <dc:creator>Alexandrova, Anastassia N.</dc:creator>
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