@article{Schneider2016Cytot-37041,
  year={2016},
  doi={10.1039/C6CC05359A},
  title={Cytotoxic heteroleptic heptacoordinate salan zirconium(IV)-bis-chelates : synthesis, aqueous stability and X-ray structure analysis},
  number={66},
  volume={52},
  issn={1359-7345},
  journal={Chemical Communications : ChemComm},
  pages={10151--10154},
  author={Schneider, Fabian and Zhao, Tiankun and Huhn, Thomas}
}

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    <dc:contributor>Zhao, Tiankun</dc:contributor>
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    <dc:creator>Schneider, Fabian</dc:creator>
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    <dcterms:title>Cytotoxic heteroleptic heptacoordinate salan zirconium(IV)-bis-chelates : synthesis, aqueous stability and X-ray structure analysis</dcterms:title>
    <dc:creator>Huhn, Thomas</dc:creator>
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    <dcterms:abstract xml:lang="eng">Herein we report the synthesis and structural characterization of a series of novel Zr(IV)salan complexes. The initial metalation product [(L1)&lt;sub&gt;2&lt;/sub&gt;Zr] is highly water sensitive while ligand exchanged [L1Zr(dipic)] hydrolyses slowly with a bis-hydroxo Zr(IV) species identified by MS as an intermediate. [L1Zr(dipic)] is cytotoxic in the range of cisplatin against two human carcinoma cell lines.</dcterms:abstract>
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