Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines

Eckermann, Ruben; Breunig, Michael; Gaich, Tanja

Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines

Dateien

Eckermann_0-370020.pdfGröße: 1.97 MBDownloads: 207

Datum

2016

Open Access-Veröffentlichung

Open Access Hybrid

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Chemical Communications : ChemComm. 2016, 52(76), pp. 11363-11365. ISSN 0009-241X. eISSN 1364-548X. Available under: doi: 10.1039/c6cc06125g

Zusammenfassung

For decades, akuammiline alkaloids have attracted synthetic chemists due to their intriguing molecular architecture. Among the different structural elements embedded in their carboskeleton, the methanoquinolizidine system constitutes the signature structural element of this alkaloid family. Herein, we describe a novel synthetic access to this system which relies on a [2,3]-Stevens rearrangement and results in the formal synthesis of strictamine.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

ECKERMANN, Ruben, Michael BREUNIG, Tanja GAICH, 2016. Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines. In: Chemical Communications : ChemComm. 2016, 52(76), pp. 11363-11365. ISSN 0009-241X. eISSN 1364-548X. Available under: doi: 10.1039/c6cc06125g

BibTex

@article{Eckermann2016Forma-37437,
  year={2016},
  doi={10.1039/c6cc06125g},
  title={Formal total synthesis of (±)-strictamine – the [2,3]-Stevens rearrangement for construction of octahydro-2H-2,8-methanoquinolizines},
  number={76},
  volume={52},
  issn={0009-241X},
  journal={Chemical Communications : ChemComm},
  pages={11363--11365},
  author={Eckermann, Ruben and Breunig, Michael and Gaich, Tanja}
}

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Universitätsbibliographie

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