@article{Jian2016-10-13Direc-36821,
  year={2016},
  doi={10.1002/anie.201607754},
  title={Direct Synthesis of Telechelic Polyethylene by Selective Insertion Polymerization},
  number={46},
  volume={55},
  issn={0570-0833},
  journal={Angewandte Chemie International Edition},
  pages={14378--14383},
  author={Jian, Zhongbao and Falivene, Laura and Boffa, Giusi and Ortega Sánchez, Sheila and Caporaso, Lucia and Grassi, Alfonso and Mecking, Stefan}
}

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/36821">
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:issued>2016-10-13</dcterms:issued>
    <dcterms:title>Direct Synthesis of Telechelic Polyethylene by Selective Insertion Polymerization</dcterms:title>
    <dc:contributor>Mecking, Stefan</dc:contributor>
    <dc:contributor>Boffa, Giusi</dc:contributor>
    <dc:language>eng</dc:language>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-01-19T08:01:41Z</dcterms:available>
    <dc:rights>terms-of-use</dc:rights>
    <dc:creator>Ortega Sánchez, Sheila</dc:creator>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/36821"/>
    <dc:creator>Mecking, Stefan</dc:creator>
    <dcterms:abstract xml:lang="eng">A single-step route to telechelic polyethylene (PE) is enabled by selective insertion polymerization. Pd(II) -catalyzed copolymerization of ethylene and 2-vinylfuran (VF) generates α,ω-di-furan telechelic polyethylene. Orthogonally reactive exclusively in-chain anhydride groups are formed by terpolymerization with carbic anhydride. Combined experimental and theoretical DFT studies reveal the key for this direct approach to telechelics to be a match of the comonomers' different electronics and bulk. Identified essential features of the comonomer are that it is an electron-rich olefin that forms an insertion product stabilized by an additional interaction, namely a π-η&lt;sup&gt;3&lt;/sup&gt; interaction for the case of VF.</dcterms:abstract>
    <dc:creator>Caporaso, Lucia</dc:creator>
    <dc:contributor>Caporaso, Lucia</dc:contributor>
    <dc:creator>Falivene, Laura</dc:creator>
    <dc:contributor>Falivene, Laura</dc:contributor>
    <dc:creator>Boffa, Giusi</dc:creator>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:creator>Grassi, Alfonso</dc:creator>
    <dc:creator>Jian, Zhongbao</dc:creator>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/36821/1/Jian_0-371107.pdf"/>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-01-19T08:01:41Z</dc:date>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dc:contributor>Jian, Zhongbao</dc:contributor>
    <dc:contributor>Grassi, Alfonso</dc:contributor>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/36821/1/Jian_0-371107.pdf"/>
    <dc:contributor>Ortega Sánchez, Sheila</dc:contributor>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
  </rdf:Description>
</rdf:RDF>