@article{Klaiber2016-10-25Maxim-36740,
  year={2016},
  doi={10.1021/acs.langmuir.6b02661},
  title={Maximizing Headgroup Repulsion : Hybrid Surfactants with Ultrahighly Charged Inorganic Heads and Their Unusual Self-Assembly},
  number={42},
  volume={32},
  issn={0743-7463},
  journal={Langmuir},
  pages={10920--10927},
  author={Klaiber, Alexander and Lanz, Cornelia and Landsmann, Steve and Gehring, Julia and Drechsler, Markus and Polarz, Sebastian}
}

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    <dc:creator>Polarz, Sebastian</dc:creator>
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    <dcterms:title>Maximizing Headgroup Repulsion : Hybrid Surfactants with Ultrahighly Charged Inorganic Heads and Their Unusual Self-Assembly</dcterms:title>
    <dc:contributor>Polarz, Sebastian</dc:contributor>
    <dc:creator>Gehring, Julia</dc:creator>
    <dcterms:abstract xml:lang="eng">Non-equilibrium states of matter are arousing huge interest based on outstanding possibilities to generate unprecedented structures with novel properties. Self-organizing soft-matter is the ideal object of study as it unifies periodic order and high dynamics. Compared to settled systems it becomes vital to realize more complex interaction patterns. A promising and intricate approach is implementing controlled balance between attractive and repulsive forces. We try to answer a fundamental question in surfactant science: How are processes like lyotropic liquid crystals and micellization affected, when head group charge becomes so large that repulsive interactions are inevitable? A particular challenge is that size and shape of the surfactant must not change. We could realize the latter by means of new hybrid surfactants with a heteropolyanion head [EW11O39]n- (E = PV, SiIV, BIII; n = 3, 4, 5). Among the unusual self-assembled structures we report about micelles of a new type with dumbbell morphology.</dcterms:abstract>
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    <dc:contributor>Landsmann, Steve</dc:contributor>
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    <dc:contributor>Drechsler, Markus</dc:contributor>
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