Mass production of bulk artificial nacre with excellent mechanical properties

Gao, Huai-Ling; Chen, Si-Ming; Mao, Li-Bo; Song, Zhao-Qiang; Yao, Hong-Bin; Cölfen, Helmut; Luo, Xi-Sheng; Zhang, Fu; Ni, Yong; Yu, Shu-Hong

Mass production of bulk artificial nacre with excellent mechanical properties

Dateien

Gao_0-422773.pdfGröße: 2.35 MBDownloads: 934

Datum

2017

Autor:innen

Gao, Huai-Ling

Chen, Si-Ming

Mao, Li-Bo

Song, Zhao-Qiang

Yao, Hong-Bin

Cölfen, Helmut

Luo, Xi-Sheng

Zhang, Fu

Ni, Yong

Yu, Shu-Hong

et al.

Open Access-Veröffentlichung

Open Access Gold

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Nature Communications. 2017, 8, 287. eISSN 2041-1723. Available under: doi: 10.1038/s41467-017-00392-z

Zusammenfassung

Various methods have been exploited to replicate nacre features into artificial structural materials with impressive structural and mechanical similarity. However, it is still very challenging to produce nacre-mimetics in three-dimensional bulk form, especially for further scale-up. Herein, we demonstrate that large-sized, three-dimensional bulk artificial nacre with comprehensive mimicry of the hierarchical structures and the toughening mechanisms of natural nacre can be facilely fabricated via a bottom-up assembly process based on laminating pre-fabricated two-dimensional nacre-mimetic films. By optimizing the hierarchical architecture from molecular level to macroscopic level, the mechanical performance of the artificial nacre is superior to that of natural nacre and many engineering materials. This bottom-up strategy has no size restriction or fundamental barrier for further scale-up, and can be easily extended to other material systems, opening an avenue for mass production of high-performance bulk nacre-mimetic structural materials in an efficient and cost-effective way for practical applications.Artificial materials that replicate the mechanical properties of nacre represent important structural materials, but are difficult to produce in bulk. Here, the authors exploit the bottom-up assembly of 2D nacre-mimetic films to fabricate 3D bulk artificial nacre with an optimized architecture and excellent mechanical properties.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

GAO, Huai-Ling, Si-Ming CHEN, Li-Bo MAO, Zhao-Qiang SONG, Hong-Bin YAO, Helmut CÖLFEN, Xi-Sheng LUO, Fu ZHANG, Yong NI, Shu-Hong YU, 2017. Mass production of bulk artificial nacre with excellent mechanical properties. In: Nature Communications. 2017, 8, 287. eISSN 2041-1723. Available under: doi: 10.1038/s41467-017-00392-z

BibTex

@article{Gao2017-12produ-40053,
  year={2017},
  doi={10.1038/s41467-017-00392-z},
  title={Mass production of bulk artificial nacre with excellent mechanical properties},
  volume={8},
  journal={Nature Communications},
  author={Gao, Huai-Ling and Chen, Si-Ming and Mao, Li-Bo and Song, Zhao-Qiang and Yao, Hong-Bin and Cölfen, Helmut and Luo, Xi-Sheng and Zhang, Fu and Ni, Yong and Yu, Shu-Hong},
  note={Article Number: 287}
}

RDF

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/40053">
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:contributor>Yao, Hong-Bin</dc:contributor>
    <dcterms:title>Mass production of bulk artificial nacre with excellent mechanical properties</dcterms:title>
    <dc:creator>Song, Zhao-Qiang</dc:creator>
    <dc:creator>Mao, Li-Bo</dc:creator>
    <dc:contributor>Chen, Si-Ming</dc:contributor>
    <dcterms:issued>2017-12</dcterms:issued>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-09-13T11:10:33Z</dcterms:available>
    <dc:creator>Chen, Si-Ming</dc:creator>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:contributor>Song, Zhao-Qiang</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:creator>Zhang, Fu</dc:creator>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/40053/3/Gao_0-422773.pdf"/>
    <dc:language>eng</dc:language>
    <dc:creator>Luo, Xi-Sheng</dc:creator>
    <dc:contributor>Ni, Yong</dc:contributor>
    <dc:creator>Yao, Hong-Bin</dc:creator>
    <dc:rights>Attribution 4.0 International</dc:rights>
    <dc:creator>Cölfen, Helmut</dc:creator>
    <dc:contributor>Zhang, Fu</dc:contributor>
    <dc:contributor>Yu, Shu-Hong</dc:contributor>
    <dc:creator>Gao, Huai-Ling</dc:creator>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/40053"/>
    <dc:contributor>Gao, Huai-Ling</dc:contributor>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/40053/3/Gao_0-422773.pdf"/>
    <dcterms:abstract xml:lang="eng">Various methods have been exploited to replicate nacre features into artificial structural materials with impressive structural and mechanical similarity. However, it is still very challenging to produce nacre-mimetics in three-dimensional bulk form, especially for further scale-up. Herein, we demonstrate that large-sized, three-dimensional bulk artificial nacre with comprehensive mimicry of the hierarchical structures and the toughening mechanisms of natural nacre can be facilely fabricated via a bottom-up assembly process based on laminating pre-fabricated two-dimensional nacre-mimetic films. By optimizing the hierarchical architecture from molecular level to macroscopic level, the mechanical performance of the artificial nacre is superior to that of natural nacre and many engineering materials. This bottom-up strategy has no size restriction or fundamental barrier for further scale-up, and can be easily extended to other material systems, opening an avenue for mass production of high-performance bulk nacre-mimetic structural materials in an efficient and cost-effective way for practical applications.Artificial materials that replicate the mechanical properties of nacre represent important structural materials, but are difficult to produce in bulk. Here, the authors exploit the bottom-up assembly of 2D nacre-mimetic films to fabricate 3D bulk artificial nacre with an optimized architecture and excellent mechanical properties.</dcterms:abstract>
    <dc:creator>Ni, Yong</dc:creator>
    <dc:contributor>Cölfen, Helmut</dc:contributor>
    <dc:contributor>Luo, Xi-Sheng</dc:contributor>
    <dc:creator>Yu, Shu-Hong</dc:creator>
    <dc:contributor>Mao, Li-Bo</dc:contributor>
    <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by/4.0/"/>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2017-09-13T11:10:33Z</dc:date>
  </rdf:Description>
</rdf:RDF>

Universitätsbibliographie

Ja