The Complexed Triphosphaallyl Radical, Cation, and Anion Family
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Angewandte Chemie International Edition. 2009, 48(14), pp. 2600-2604. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200805892
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Radically complex: The photolytic reaction of [CpP{W(CO)5}2] (Cp=C5Me5) with a diphosphene produces, via a radical intermediate, an air-stable complexed triphosphaallyl radical, in which the unpaired electron is evenly distributed over both terminal P atoms. Oxidation of the radical leads to a triphosphaallyl cation, which is only stable at low temperatures in solution, whereas the stable triphosphaallyl anion is formed by reduction (see picture, Mes*=2,4,6-tri-tert-butylphenyl).
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SCHEER, Manfred, Christian KUNTZ, Markus STUBENHOFER, Michael LINSEIS, Rainer F. WINTER, Marek SIERKA, 2009. The Complexed Triphosphaallyl Radical, Cation, and Anion Family. In: Angewandte Chemie International Edition. 2009, 48(14), pp. 2600-2604. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200805892BibTex
@article{Scheer2009Compl-13794, year={2009}, doi={10.1002/anie.200805892}, title={The Complexed Triphosphaallyl Radical, Cation, and Anion Family}, number={14}, volume={48}, issn={1433-7851}, journal={Angewandte Chemie International Edition}, pages={2600--2604}, author={Scheer, Manfred and Kuntz, Christian and Stubenhofer, Markus and Linseis, Michael and Winter, Rainer F. and Sierka, Marek} }
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