@article{Siemeling2005-02-02Inter-13806,
  year={2005},
  doi={10.1021/ja0436244},
  title={The Interaction of 1,1‘-Diisocyanoferrocene with Gold: Formation of Monolayers and Supramolecular Polymerization of an Aurophilic Ferrocenophane},
  number={4},
  volume={127},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={1102--1103},
  author={Siemeling, Ulrich and Rother, Dag and Bruhn, Clemens and Fink, Heinrich and Weidner, Tobias and Träger, Frank and Rothenberger, Alexander and Fenske, Dieter and Priebe, Andreas and Maurer, Jörg and Winter, Rainer F.}
}

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    <dc:creator>Träger, Frank</dc:creator>
    <dc:creator>Priebe, Andreas</dc:creator>
    <dc:contributor>Weidner, Tobias</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-22T09:52:38Z</dcterms:available>
    <dc:contributor>Träger, Frank</dc:contributor>
    <dc:contributor>Fenske, Dieter</dc:contributor>
    <dcterms:bibliographicCitation>First publ. in: Journal of the American Chemical Society 127 (2005), 4, pp. 1102-1103</dcterms:bibliographicCitation>
    <dc:creator>Siemeling, Ulrich</dc:creator>
    <dc:contributor>Fink, Heinrich</dc:contributor>
    <dc:contributor>Siemeling, Ulrich</dc:contributor>
    <dc:creator>Fenske, Dieter</dc:creator>
    <dc:creator>Maurer, Jörg</dc:creator>
    <dcterms:abstract xml:lang="eng">The coordination chemistry of 1,1‘-diisocyanoferrocene (1) was investigated. Its reaction with Cr(CO)5(THF) (2 equiv) affords (1)[Cr(CO)5]2, which exhibits eclipsed cyclopentadienyl rings with a synclinal arrangement of the two substituents. 1 behaves like an aryl isocyanide in this compound according to IR spectroscopic data, and its oxidation leads to a marked decrease of net electron donor ability. The reaction of 1 with AuCl(SMe2) affords the insoluble coordination polymer [(1)(AuCl)2]∞. The (1)(AuCl)2 molecules adopt a 3,4-diaura-[6]ferrocenophane structure. They are aggregated in a zipperlike fashion through aurophilic interactions, with Au−Au distances ranging from 3.34 to 3.48 Å. The adsorption of 1 from acetonitrile solution on polycrystalline gold affords a self-assembled monolayer. Both isocyanide groups are binding to the surface.</dcterms:abstract>
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    <dc:contributor>Rothenberger, Alexander</dc:contributor>
    <dc:contributor>Rother, Dag</dc:contributor>
    <dcterms:issued>2005-02-02</dcterms:issued>
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    <dc:contributor>Priebe, Andreas</dc:contributor>
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    <dc:creator>Weidner, Tobias</dc:creator>
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    <dc:contributor>Bruhn, Clemens</dc:contributor>
    <dc:creator>Rother, Dag</dc:creator>
    <dcterms:title>The Interaction of 1,1‘-Diisocyanoferrocene with Gold: Formation of Monolayers and Supramolecular Polymerization of an Aurophilic Ferrocenophane</dcterms:title>
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    <dc:creator>Rothenberger, Alexander</dc:creator>
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    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-22T09:52:38Z</dc:date>
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