@article{Roder2002Combi-13813,
  year={2002},
  doi={10.1016/S0022-328X(01)01298-0},
  title={Combining organometallic and Werner-type coordination sites in highly preorganized heterobimetallic systems},
  number={1-2},
  volume={641},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={113--120},
  author={Röder, Jens C. and Meyer, Franc and Winter, Rainer F. and Kaifer, Elisabeth},
  note={Supplemental material: http://www.ccdc.cam.ac.uk}
}

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    <dc:language>eng</dc:language>
    <dc:creator>Kaifer, Elisabeth</dc:creator>
    <dcterms:bibliographicCitation>First publ. in: Journal of Organometallic Chemistry 641 (2002), 1/2, pp. 113-120</dcterms:bibliographicCitation>
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    <dc:contributor>Meyer, Franc</dc:contributor>
    <dc:contributor>Röder, Jens C.</dc:contributor>
    <dcterms:issued>2002</dcterms:issued>
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    <dcterms:title>Combining organometallic and Werner-type coordination sites in highly preorganized heterobimetallic systems</dcterms:title>
    <dc:creator>Meyer, Franc</dc:creator>
    <dc:creator>Röder, Jens C.</dc:creator>
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    <dc:contributor>Kaifer, Elisabeth</dc:contributor>
    <dc:creator>Winter, Rainer F.</dc:creator>
    <dc:contributor>Winter, Rainer F.</dc:contributor>
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    <dcterms:abstract xml:lang="eng">A first example of a novel class of preorganized bimetallic complexes is reported, in which both an organometallic CpMn(CO)2 fragment and a classical Werner-type coordination site are arranged in close proximity by means of a bridging pyrazolate. The synthetic route starts from N-protected bis(chloromethyl)pyrazole and involves sequential attachment of the manganese part and the chelating N-donor compartment, bis(pyridylmethyl)amine, at the different sides of the ligand backbone. Pyrazole binding to the manganese(I) is achieved by photoinduced substitution of CO, and the adjacent N4-coordination pocket is suited to accommodate a second metal ion. The heterodinuclear MnZn complex 4 is characterized crystallographically and its redox chemistry investigated by spectroelectrochemical methods.</dcterms:abstract>
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