Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin

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2008
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Sarkar, Biprajit
Kaim, Wolfgang
Zális, Stanislav
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Organometallics. 2008, 27(14), pp. 3321-3324. ISSN 0276-7333. Available under: doi: 10.1021/om8003338
Zusammenfassung

The tetrakis(4-styryl)ethene (TSTE 4−)-bridged tetraruthenium complex [{(P i Pr 3) 2(CO)ClRu} 4{μ 4-(CHCHC 6H 4) 4(CC)}] undergoes four consecutive oxidations at low potential. The ligand-dominated nature of these processes is confirmed by spectroscopic and quantum-chemical investigations.

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ISO 690LINSEIS, Michael, Rainer F. WINTER, Biprajit SARKAR, Wolfgang KAIM, Stanislav ZÁLIS, 2008. Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin. In: Organometallics. 2008, 27(14), pp. 3321-3324. ISSN 0276-7333. Available under: doi: 10.1021/om8003338
BibTex
@article{Linseis2008Ligan-13824,
  year={2008},
  doi={10.1021/om8003338},
  title={Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin},
  number={14},
  volume={27},
  issn={0276-7333},
  journal={Organometallics},
  pages={3321--3324},
  author={Linseis, Michael and Winter, Rainer F. and Sarkar, Biprajit and Kaim, Wolfgang and Zális, Stanislav}
}
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