@article{Winter2000Synth-13855,
  year={2000},
  doi={10.1002/(SICI)1521-3749(200005)626:5<1196::AID-ZAAC1196>3.0.CO;2-B},
  title={Synthesis, Structures, Ligand Substitution Reactions, and Electrochemistry of the Nitrile Complexes cis-[Ru(dppm)2Cl(NCR)]+ PF6– (dppm = Bis(diphenylphosphino)methane, R = CH3, C2H5, tBu, Ph)},
  number={5},
  volume={626},
  issn={0044-2313},
  journal={Zeitschrift für anorganische und allgemeine Chemie},
  pages={1196--1204},
  author={Winter, Rainer F. and Scheiring, Thomas}
}

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    <dc:contributor>Winter, Rainer F.</dc:contributor>
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    <dc:contributor>Scheiring, Thomas</dc:contributor>
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    <dc:language>eng</dc:language>
    <dc:creator>Scheiring, Thomas</dc:creator>
    <dcterms:bibliographicCitation>First publ. in: Zeitschrift für anorganische und allgemeine Chemie 626 (2000), 5, pp. 1196–1204</dcterms:bibliographicCitation>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-27T13:59:51Z</dc:date>
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    <dcterms:alternative>Synthese, Strukturen, Ligandenaustauschreaktionen und Elektrochemisches Verhalten der Nitrilkomplexe cis-[Ru(dppm)2Cl(NCR)]+ PF6– (dppm = Bis(diphenylphosphino)methan, R = CH3, C2H5, tBu, Ph)</dcterms:alternative>
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    <dcterms:abstract xml:lang="eng">Isomerically pure nitrile complexes cis-[Ru(dppm)2Cl(NCR)]+ (2 a–d) are formed upon chloride displacement from cis-[Ru(dppm)2Cl2] (1) or, alternatively, by ligand substitution from the acetonitrile complex 2 a. This latter approach does also allow for the introduction of pyridine (3 a,b), heptamethyldisilazane (4) or isonitrile ligands (5). All complexes are obtained as the configurationally stable cis-isomers. Only cis-[Ru(dppm)2Cl(CNtBu)]+ slowly isomerizes to the trans from. The solid state structures of the CH3CN, C2H5CN and the trans-tBuNC complexes were established by X-ray crystallography. Electrochemical investigations of the nitrile complexes 2 a–d show in addition to a chemically reversible one-electron oxidation an irrversible reduction step. In CH2Cl2 solution, cis- and trans-[Ru(dppm)2Cl2] have been identified as the final products of the electrochemically induced reaction sequence.</dcterms:abstract>
    <dc:creator>Winter, Rainer F.</dc:creator>
    <dcterms:title>Synthesis, Structures, Ligand Substitution Reactions, and Electrochemistry of the Nitrile Complexes cis-[Ru(dppm)2Cl(NCR)]+ PF6– (dppm = Bis(diphenylphosphino)methane, R = CH3, C2H5, tBu, Ph)</dcterms:title>
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