@article{Trzaskowski2011-09-01Aliph-17555,
  year={2011},
  doi={10.1002/marc.201100319},
  title={Aliphatic long-chain C 20 polyesters from Olefin metathesis},
  number={17},
  volume={32},
  issn={1022-1336},
  journal={Macromolecular Rapid Communications},
  pages={1352--1356},
  author={Trzaskowski, Justyna and Quinzler, Dorothee and Bährle, Christian and Mecking, Stefan}
}

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    <dcterms:abstract xml:lang="eng">Self-metathesis of undecenoic acid with [(PCy3)2Cl2Ru=CHPh] (2), followed by exhaustive hydrogenation yielded pure 1,20-eicosanedioic acid (5) (&gt;99%) free of side-products from isomerization. Polycondensation with eicosane-1,20-diol (6), formed by reduction of the diol, yielded polyester 20,20 (Tm = 108 °C). By comparison, the known ADMET polymerization of undec-10-enyl undec-10-enoate (7), and subsequent exhaustive polymer-analogous hydrogenation yielded a polyester (poly-8) with irregular structure of the ester groups in the polymer chain (-O(C=O)[BOND] vs. -C(=O)O-) (Tm = 103 °C). Hydrogenation of secondary dispersions of poly-7 yielded aqueous dispersions of the long-chain aliphatic polyester poly-8.</dcterms:abstract>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-01-13T13:29:28Z</dc:date>
    <dc:contributor>Bährle, Christian</dc:contributor>
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    <dcterms:bibliographicCitation>First publ. in: Macromolecular Rapid Communications ; 32 (2011), 17. - S. 1352-1356</dcterms:bibliographicCitation>
    <dcterms:title>Aliphatic long-chain C 20 polyesters from Olefin metathesis</dcterms:title>
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    <dc:creator>Mecking, Stefan</dc:creator>
    <dc:creator>Bährle, Christian</dc:creator>
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    <dc:contributor>Mecking, Stefan</dc:contributor>
    <dc:creator>Quinzler, Dorothee</dc:creator>
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    <dc:contributor>Trzaskowski, Justyna</dc:contributor>
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