Polymer precursors from catalytic reactions of natural oils

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2012
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Furst, Marc R. L.
Goff, Ronan Le
Botting, Catherine H.
Cole-Hamilton, David J.
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Green Chem.. 2012, 14(2), pp. 472-477. ISSN 1463-9262. Available under: doi: 10.1039/C1GC16094J
Zusammenfassung

Dimethyl 1,19-nonadecanedioate is produced from the methoxycarbonylation of commercial olive, rapeseed or sunflower oils in the presence of a catalyst derived from [Pd2(dba)3], bis(ditertiarybutylphosphinomethyl)benzene (BDTBPMB) and methanesulphonic acid (MSA). The diester is then hydrogenated to 1,19-nonadecanediol using Ru/1,1,1-tris-(diphenylphosphinemethyl)ethane (triphos). 1,19-Nonadecadienoic acid is hydrogenated to short chain oligoesters, which can themselves be hydrogenated to 1,19-nonadecanol by hydrogenation in the presence of water.

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ISO 690FURST, Marc R. L., Ronan Le GOFF, Dorothee QUINZLER, Stefan MECKING, Catherine H. BOTTING, David J. COLE-HAMILTON, 2012. Polymer precursors from catalytic reactions of natural oils. In: Green Chem.. 2012, 14(2), pp. 472-477. ISSN 1463-9262. Available under: doi: 10.1039/C1GC16094J
BibTex
@article{Furst2012Polym-18701,
  year={2012},
  doi={10.1039/C1GC16094J},
  title={Polymer precursors from catalytic reactions of natural oils},
  number={2},
  volume={14},
  issn={1463-9262},
  journal={Green Chem.},
  pages={472--477},
  author={Furst, Marc R. L. and Goff, Ronan Le and Quinzler, Dorothee and Mecking, Stefan and Botting, Catherine H. and Cole-Hamilton, David J.}
}
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    <dcterms:abstract xml:lang="eng">Dimethyl 1,19-nonadecanedioate is produced from the methoxycarbonylation of commercial olive, rapeseed or sunflower oils in the presence of a catalyst derived from [Pd&lt;sub&gt;2&lt;/sub&gt;(dba)&lt;sub&gt;3&lt;/sub&gt;], bis(ditertiarybutylphosphinomethyl)benzene (BDTBPMB) and methanesulphonic acid (MSA). The diester is then hydrogenated to 1,19-nonadecanediol using Ru/1,1,1-tris-(diphenylphosphinemethyl)ethane (triphos). 1,19-Nonadecadienoic acid is hydrogenated to short chain oligoesters, which can themselves be hydrogenated to 1,19-nonadecanol by hydrogenation in the presence of water.</dcterms:abstract>
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