@article{Moller2012-01-16origi-18702,
  year={2012},
  doi={10.1002/chem.201102408},
  title={The origin of living polymerization with an o-fluorinated catalyst : NMR spectroscopic characterization of chain-carrying species},
  number={3},
  volume={18},
  issn={0947-6539},
  journal={Chemistry - A European Journal},
  pages={848--856},
  author={Möller, Heiko M. and Baier, Moritz C. and Mecking, Stefan and Talsi, Evgenii P. and Bryliakov, Konstantin P.}
}

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/18702">
    <dc:language>eng</dc:language>
    <dc:creator>Talsi, Evgenii P.</dc:creator>
    <dcterms:bibliographicCitation>First publ. in: Chemistry : a European journal ; 18 (2012), 3. - S. 848-856</dcterms:bibliographicCitation>
    <dc:creator>Möller, Heiko M.</dc:creator>
    <dc:rights>terms-of-use</dc:rights>
    <dc:creator>Bryliakov, Konstantin P.</dc:creator>
    <dc:contributor>Talsi, Evgenii P.</dc:contributor>
    <dc:contributor>Mecking, Stefan</dc:contributor>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/18702"/>
    <dcterms:issued>2012-01-16</dcterms:issued>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-03-20T20:26:22Z</dc:date>
    <dc:creator>Baier, Moritz C.</dc:creator>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dc:contributor>Möller, Heiko M.</dc:contributor>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-03-20T20:26:22Z</dcterms:available>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/18702/2/M%c3%b6ller_187027.pdf"/>
    <dc:contributor>Bryliakov, Konstantin P.</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:title>The origin of living polymerization with an o-fluorinated catalyst : NMR spectroscopic characterization of chain-carrying species</dcterms:title>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:contributor>Baier, Moritz C.</dc:contributor>
    <dc:creator>Mecking, Stefan</dc:creator>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/18702/2/M%c3%b6ller_187027.pdf"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:abstract xml:lang="eng">To characterize the origin of living polymerization with nonmetallocene titanium-based catalysts containing o-fluoroaryl substituents, ethene polymerization by an o-fluorinated bis(enolatoimine) titanium catalyst and its nonfluorinated counterpart has been studied by multinuclear NMR spectroscopy by using methylaluminoxane (MAO) or AlMe&lt;sub&gt;3&lt;/sub&gt;/CPh&lt;sub&gt;3&lt;/sub&gt;B(C&lt;sub&gt;6&lt;/sub&gt;F&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;4&lt;/sub&gt; as activators. Formation of ion pairs of the type [TiL&lt;sub&gt;2&lt;/sub&gt;Me][MeMAO] and [TiL&lt;sub&gt;2&lt;/sub&gt;Me][B(C&lt;sub&gt;6&lt;/sub&gt;F&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;4&lt;/sub&gt;] has been observed for both catalysts. These ion pairs react with ethene to afford the chain-propagating species [TiL&lt;sub&gt;2&lt;/sub&gt;P][MeMAO] and [TiL&lt;sub&gt;2&lt;/sub&gt;P][B(C&lt;sub&gt;6&lt;/sub&gt;F&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;4&lt;/sub&gt;], respectively (P=growing polymeryl chain). For the o-F-substituted catalyst species of the second type, NMR spectroscopy provides evidence that the o-F substituents interact with the metal center. This interaction is proposed to keep the polymerization catalysis living by suppressing chain transfer to AlMe&lt;sub&gt;3&lt;/sub&gt; and β-hydrogen transfer processes.</dcterms:abstract>
  </rdf:Description>
</rdf:RDF>