@article{Rochette2011Annea-19284,
  year={2011},
  doi={10.1021/ma2003213},
  title={Annealing of single lamella nanoparticles of polyethylene},
  number={12},
  volume={44},
  issn={0024-9297},
  journal={Macromolecules},
  pages={4845--4851},
  author={Rochette, Christophe N. and Rosenfeldt, Sabine and Henzler, Katja and Polzer, Frank and Ballauff, Matthias and Tong, Qiong and Mecking, Stefan and Drechsler, Markus and Narayanan, Theyencheri and Harnau, Ludger}
}

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    <dc:contributor>Mecking, Stefan</dc:contributor>
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    <dcterms:bibliographicCitation>First publ. in: Macromolecules ; 44 (2011), 12. - S. 4845-4851</dcterms:bibliographicCitation>
    <dc:contributor>Henzler, Katja</dc:contributor>
    <dc:contributor>Polzer, Frank</dc:contributor>
    <dc:creator>Rochette, Christophe N.</dc:creator>
    <dc:creator>Mecking, Stefan</dc:creator>
    <dc:contributor>Narayanan, Theyencheri</dc:contributor>
    <dc:contributor>Harnau, Ludger</dc:contributor>
    <dc:contributor>Rosenfeldt, Sabine</dc:contributor>
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    <dc:creator>Drechsler, Markus</dc:creator>
    <dc:contributor>Rochette, Christophe N.</dc:contributor>
    <dc:contributor>Drechsler, Markus</dc:contributor>
    <dc:creator>Polzer, Frank</dc:creator>
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    <dc:contributor>Tong, Qiong</dc:contributor>
    <dc:contributor>Ballauff, Matthias</dc:contributor>
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    <dcterms:title>Annealing of single lamella nanoparticles of polyethylene</dcterms:title>
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    <dc:creator>Ballauff, Matthias</dc:creator>
    <dc:creator>Narayanan, Theyencheri</dc:creator>
    <dc:creator>Tong, Qiong</dc:creator>
    <dcterms:abstract xml:lang="eng">We study the change of the size and structure of freely suspended single lamella nanoparticles of polyethylene during thermal annealing in aqueous solutions. Using small-angle X-ray scattering and cryogenic transmission electron microscopy, it is shown that a doubling of the crystalline lamella sandwiched between two amorphous polymer layers is obtained by annealing the nanoparticles at 125 °C. This thickening of the crystalline lamella can be understood in terms of an unlooping of polymer chains within a single nanoparticle. In addition, a variation of the annealing temperature from 90 to 115 °C demonstrates that the inverse of the crystalline lamellar thickness increases linearly with the annealing temperatures leading to a recrystallization line in a Gibbs–Thomson graph. Since the nanoparticles consist of about only eight polymer chains, they can be considered as a ideal candidates for the experimental realization of equilibrium polymer crystals.</dcterms:abstract>
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    <dc:creator>Harnau, Ludger</dc:creator>
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    <dc:creator>Rosenfeldt, Sabine</dc:creator>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2012-05-11T08:42:45Z</dc:date>
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