@article{Reiter2021-07-15Tunin-54801,
  year={2021},
  doi={10.1002/pol.20210200},
  title={Tuning the glass transition of siloxane-based poly(ionic liquid)s towards high ion conductivity},
  number={14},
  volume={59},
  issn={2642-4150},
  journal={Journal of Polymer Science},
  pages={1518--1527},
  author={Reiter, Manuel and Anton, Arthur Markus and Chang, Jian and Kremer, Friedrich and Unterlass, Miriam M. and Yuan, Jiayin}
}

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    <dc:creator>Yuan, Jiayin</dc:creator>
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    <dc:creator>Kremer, Friedrich</dc:creator>
    <dc:creator>Anton, Arthur Markus</dc:creator>
    <dc:creator>Reiter, Manuel</dc:creator>
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    <dc:contributor>Reiter, Manuel</dc:contributor>
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    <dc:contributor>Chang, Jian</dc:contributor>
    <dc:creator>Unterlass, Miriam M.</dc:creator>
    <dcterms:title>Tuning the glass transition of siloxane-based poly(ionic liquid)s towards high ion conductivity</dcterms:title>
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    <dc:rights>Attribution 4.0 International</dc:rights>
    <dc:contributor>Unterlass, Miriam M.</dc:contributor>
    <dc:contributor>Kremer, Friedrich</dc:contributor>
    <dc:contributor>Anton, Arthur Markus</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2021-09-03T07:59:55Z</dc:date>
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    <dc:creator>Chang, Jian</dc:creator>
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    <dcterms:abstract xml:lang="eng">Herein, we report a simple and versatile synthetic approach towards siloxane-based poly(ionic liquid)s (PILs) with unusually low glass transition temperatures (T&lt;sub&gt;g&lt;/sub&gt;) down to −73°C, and thus “liquid-like” behavior at room temperature. We designed a polydimethylsiloxane-derived copolymer carrying dialkylimidazolium moieties, and by careful selection of the side-chain length and the type of anions we were able to manipulate its T&lt;sub&gt;g&lt;/sub&gt; over a wide range and reach high ionic conductivities (σ&lt;sub&gt;DC&lt;/sub&gt;) up to 4.8 × 10&lt;sup&gt;−5 &lt;/sup&gt;S/cm at 300 K. The ionized species make up only a minor fraction (&lt;25 mol%) of the overall repeating units and are supposedly randomly distributed: Yet our results indicate dramatic effects on the thermal properties due to repulsive interactions between ionic and non-ionic segments.</dcterms:abstract>
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