A study of various methods for the analysis of the phophosilicate glass layer

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27th European Photovoltaic Solar Energy Conference and Exhibition. München: WIP Renewable Energies, 2012, pp. 1325-1328. ISBN 3-936338-28-0. Available under: doi: 10.4229/27thEUPVSEC2012-2BV.5.1
Zusammenfassung

The understanding and therefore the optimization of n+-emitter formation in crystalline silicon using POCl3-diffusion requires a more detailed knowledge of the dopant source: the PhosphoSilicate Glass (PSG) layer. The growth of PSG during the phosphorus diffusion process depends on several process parameters, such as temperature, duration, POCl3-N2 and O2 gas flows. In this work, we compare the uncertainties in various methods for PSG thickness measurements: by an Atomic Force Microscope (AFM), a profilometer, a Scanning Electron Microscope (SEM) and a spectroscopic ellipsometer. We then quantify how the PSG thickness is influenced by the process parameters. We also measure the total amount of phosphorus (P-dose) in the PSG layer using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) and quantify the P dose in dependence of the process parameters as well. Finally, by combining both the measured PSG thickness and the dose, we successfully determine a lower limit for the phosphorus concentration in the PSG layer. It is, depending on the process parameters, between 7x1021 cm-3 and 1.2x1022 cm-3, which is a remarkably narrow range. These results will help to improve the phosphorus diffusion model by considering both the PSG growth behavior and PSG composition, and so will facilitate the development of a predictive model for the POCl3 diffusions process.

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530 Physik
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27th European Photovoltaic Solar Energy Conference and Exhibition, 24. Sep. 2012 - 28. Sep. 2012, Frankfurt, Germany
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ISO 690STEYER, Michael, Amir DASTGHEIB-SHIRAZI, Hannes WAGNER, Gabriel MICARD, Pietro ALTERMATT, Giso HAHN, 2012. A study of various methods for the analysis of the phophosilicate glass layer. 27th European Photovoltaic Solar Energy Conference and Exhibition. Frankfurt, Germany, 24. Sep. 2012 - 28. Sep. 2012. In: 27th European Photovoltaic Solar Energy Conference and Exhibition. München: WIP Renewable Energies, 2012, pp. 1325-1328. ISBN 3-936338-28-0. Available under: doi: 10.4229/27thEUPVSEC2012-2BV.5.1
BibTex
@inproceedings{Steyer2012study-22522,
  year={2012},
  doi={10.4229/27thEUPVSEC2012-2BV.5.1},
  title={A study of various methods for the analysis of the phophosilicate glass layer},
  isbn={3-936338-28-0},
  publisher={WIP Renewable Energies},
  address={München},
  booktitle={27th European Photovoltaic Solar Energy Conference and Exhibition},
  pages={1325--1328},
  author={Steyer, Michael and Dastgheib-Shirazi, Amir and Wagner, Hannes and Micard, Gabriel and Altermatt, Pietro and Hahn, Giso},
  note={DVD-Ausgabe}
}
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