Distinct methylalumoxane(MAO)-derived Me–MAO− anions in contact with a zirconocenium cation—a 13C-NMR study
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Zirconocenium cations of the type [(MeC5H4)2ZrMe]+, formed by excess methylalumoxane (MAO) from (MeC5H4)2ZrCl2 or (MeC5H4)2ZrMe2 with 13C-labelled ring ligands, are found to form ion pairs with two types of anions, Me–MAOA− and Me–MAOB−, which differ in their coordinative strengths: More strongly coherent ion pairs [(MeC5H4)2ZrMe+***Me–MAOB−] are converted to more easily separable ion pairs [(MeC5H4)2ZrMe+***Me–MAOA−] by a sufficient excess of MAO. These react with Al2Me6 to form outer-sphere ion pairs containing the cationic AlMe3 adduct [(MeC5H4)2Zr(µ-Me)2AlMe2]+; formation of the more easily separable ion pairs might be required also for polymerisation catalysis.
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BABUSHKIN, Dmitrii E., Corinna NAUNDORF, Hans-Herbert BRINTZINGER, 2006. Distinct methylalumoxane(MAO)-derived Me–MAO− anions in contact with a zirconocenium cation—a 13C-NMR study. In: Dalton Transactions. 2006(38), pp. 4539-4544. ISSN 1477-9226. eISSN 1477-9234. Available under: doi: 10.1039/B611028MBibTex
@article{Babushkin2006-10-14Disti-23673, year={2006}, doi={10.1039/B611028M}, title={Distinct methylalumoxane(MAO)-derived Me–MAO<sup>−</sup> anions in contact with a zirconocenium cation—a <sup>13</sup>C-NMR study}, number={38}, issn={1477-9226}, journal={Dalton Transactions}, pages={4539--4544}, author={Babushkin, Dmitrii E. and Naundorf, Corinna and Brintzinger, Hans-Herbert} }
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