Bis(Eta3-indenyl)bis(tetrahydrofuran)magnesium(II)

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2004
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Gritzo, Holger
Schaper, Frank
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Acta Crystallographica Section E Structure Reports Online. 2004, 60(8), pp. m1108-m1110. ISSN 1600-5368. Available under: doi: 10.1107/S1600536804016149
Zusammenfassung

In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between Eta1- and Eta3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetrahydrofuran). A crystallographic C2 axis bisects the O-Mg-O angle.

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ISO 690GRITZO, Holger, Frank SCHAPER, Hans-Herbert BRINTZINGER, 2004. Bis(Eta3-indenyl)bis(tetrahydrofuran)magnesium(II). In: Acta Crystallographica Section E Structure Reports Online. 2004, 60(8), pp. m1108-m1110. ISSN 1600-5368. Available under: doi: 10.1107/S1600536804016149
BibTex
@article{Gritzo2004BisEt-23845,
  year={2004},
  doi={10.1107/S1600536804016149},
  title={Bis(Eta<sup>3</sup>-indenyl)bis(tetrahydrofuran)magnesium(II)},
  number={8},
  volume={60},
  issn={1600-5368},
  journal={Acta Crystallographica Section E Structure Reports Online},
  pages={m1108--m1110},
  author={Gritzo, Holger and Schaper, Frank and Brintzinger, Hans-Herbert}
}
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    <dcterms:abstract xml:lang="eng">In the crystal structure of the title compound, [Mg(C&lt;sub&gt;4&lt;/sub&gt;H&lt;sub&gt;8&lt;/sub&gt;O)&lt;sub&gt;2&lt;/sub&gt;(C&lt;sub&gt;9&lt;/sub&gt;H&lt;sub&gt;7&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;], the two indenyl ligands are bound to the Mg atom in a manner intermediate between Eta&lt;sup&gt;1&lt;/sup&gt;- and Eta&lt;sup&gt;3&lt;/sup&gt;-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)&lt;sub&gt;2&lt;/sub&gt; adduct (THF is tetrahydrofuran). A crystallographic C&lt;sub&gt;2&lt;/sub&gt; axis bisects the O-Mg-O angle.</dcterms:abstract>
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