@article{Huttenloch1997ansam-23890,
  year={1997},
  doi={10.1016/S0022-328X(97)00064-8},
  title={ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation},
  number={1-2},
  volume={541},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={219--232},
  author={Huttenloch, Monika E. and Dorer, Birgit and Rief, Ursula and Prosenc, Marc-Heinrich and Schmidt, Katrin and Brintzinger, Hans-Herbert}
}

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    <dcterms:bibliographicCitation>Journal of Organometallic Chemistry ; 541 (1997), 1-2. - S. 219-232</dcterms:bibliographicCitation>
    <dcterms:abstract xml:lang="eng">Chiral, biphenyl-bridged metallocene complexes of general type biph(3,4-R&lt;sub&gt;2&lt;/sub&gt;C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;2&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;MCl&lt;sub&gt;2&lt;/sub&gt; (biph = 1,1'-biphenyldiyl) were synthesized and characterized. For the dimethyl-substituted titanocenes and zirconocenes (R = CH&lt;sub&gt;3&lt;/sub&gt;; M = Ti, Zr), preparations with increased overall yields and an optical resolution method were developed. The bis(2-tetrahydroindenyl) complexes (R,R = (CH&lt;sub&gt;2&lt;/sub&gt;)4; M = Ti, Zr) were obtained by an alternative synthetic route and characterized with regard to their crystal structures. Syntheses of the phenyl-substituted derivatives (R = C&lt;sub&gt;6&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;; M = Ti, Zr) and of a chiral, methyl-substituted vanadocene complex (R = CH&lt;sub&gt;3&lt;/sub&gt;; M = V) are also reported.</dcterms:abstract>
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    <dc:contributor>Prosenc, Marc-Heinrich</dc:contributor>
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    <dc:creator>Rief, Ursula</dc:creator>
    <dc:creator>Brintzinger, Hans-Herbert</dc:creator>
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    <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor>
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    <dc:creator>Huttenloch, Monika E.</dc:creator>
    <dc:creator>Schmidt, Katrin</dc:creator>
    <dc:contributor>Rief, Ursula</dc:contributor>
    <dcterms:issued>1997</dcterms:issued>
    <dc:creator>Prosenc, Marc-Heinrich</dc:creator>
    <dc:contributor>Schmidt, Katrin</dc:contributor>
    <dc:creator>Dorer, Birgit</dc:creator>
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    <dcterms:title>ansa-metallocene derivatives XXXIX biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium : syntheses, crystal structures and enantioseparation</dcterms:title>
    <dc:contributor>Huttenloch, Monika E.</dc:contributor>
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