@article{Burger1991ansam-23945,
  year={1991},
  doi={10.1016/0022-328X(91)86118-A},
  title={ansa-metallocene derivatives : XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction},
  number={2},
  volume={407},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={207--213},
  author={Burger, Peter and Brintzinger, Hans-Herbert}
}

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    <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor>
    <dcterms:bibliographicCitation>Journal of Organometallic Chemistry ; 407 (1991), 2. - S. 207-213</dcterms:bibliographicCitation>
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    <dcterms:title>ansa-metallocene derivatives : XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction</dcterms:title>
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    <dc:creator>Burger, Peter</dc:creator>
    <dc:creator>Brintzinger, Hans-Herbert</dc:creator>
    <dc:contributor>Burger, Peter</dc:contributor>
    <dcterms:abstract xml:lang="eng">Novel olefin-linked biscyclopentadienyl ligands have been prepared by McMurry coupling reactions of benzoyl- and acetyl-cyclopentadienyl sodium. Reactions of the disodium salts with TiCl&lt;sub&gt;4&lt;/sub&gt; or TiCl&lt;sub&gt;3&lt;/sub&gt; · 3THF afford the alkene-bridged ansa-titanocene dichlorides. &lt;sup&gt;13&lt;/sup&gt;C-NMR shifts to the bridge carbon atoms do not indicate any interaction between the olefin π-system and the metal.</dcterms:abstract>
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    <dcterms:issued>1991</dcterms:issued>
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