@article{Smith1981Ansam-23955,
  year={1981},
  doi={10.1016/S0022-328X(00)86097-0},
  title={Ansa-metallocene derivatives : III. Influence of an interannular ethylene bridge on the reactivity of titanocene derivatives},
  number={2},
  volume={218},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={159--167},
  author={Smith, James A. and Brintzinger, Hans-Herbert}
}

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    <dc:creator>Brintzinger, Hans-Herbert</dc:creator>
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    <dcterms:abstract xml:lang="eng">Titanocene derivatives with an interannular ethylene bridge, while resembling their unbridged counterparts in many transformations involving Ti&lt;sup&gt;IV&lt;/sup&gt; or Ti&lt;sup&gt;llI&lt;/sup&gt; oxidation stages, do not follow reaction paths previously observed for unbridged titanocene in a number of reactions, such as formation of a Ti&lt;sup&gt;II&lt;/sup&gt; dinitrogen complex, isotope exchange of the cyclopentadienyl riIig ligands with D&lt;sub&gt;2&lt;/sub&gt;, or formation of a Ti&lt;sup&gt;III&lt;/sup&gt; hydride compound. These reactions are considered to be blocked by the unavailability of a «free" titanocene species, [(CH&lt;sub&gt;2&lt;/sub&gt;) sub&gt;2&lt;/sub&gt;-(C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;Ti&lt;sup&gt;II&lt;/sup&gt;]&lt;sub&gt;n&lt;/sub&gt;, as an intermediate in such systems.</dcterms:abstract>
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    <dcterms:bibliographicCitation>Journal of Organometallic Chemistry ; 218 (1981), 2. - S. 159-167</dcterms:bibliographicCitation>
    <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor>
    <dc:creator>Smith, James A.</dc:creator>
    <dc:contributor>Smith, James A.</dc:contributor>
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