@article{Monkeberg1989COind-23960,
  year={1989},
  doi={10.1016/0022-328X(89)87027-5},
  title={CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes : Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis},
  number={3},
  volume={365},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={285--295},
  author={Mönkeberg, Sigrid and van Raaij, Edith and Kiesele, Herbert and Brintzinger, Hans-Herbert}
}

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    <dc:contributor>van Raaij, Edith</dc:contributor>
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    <dcterms:title>CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes : Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis</dcterms:title>
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    <dc:contributor>Mönkeberg, Sigrid</dc:contributor>
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    <dc:contributor>Brintzinger, Hans-Herbert</dc:contributor>
    <dcterms:issued>1989</dcterms:issued>
    <dc:creator>Kiesele, Herbert</dc:creator>
    <dc:contributor>Kiesele, Herbert</dc:contributor>
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    <dcterms:abstract xml:lang="eng">Infrared studies at a CO pressure of 120 bar show (η&lt;sup&gt;5&lt;/sup&gt;-C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;W(CO) to be completely resistant to an excess of CO in the absence of oxidants, but cyclovoltammetric measurements with this complex and with (η&lt;sup&gt;3&lt;/sup&gt;-C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)(η&lt;sup&gt;5&lt;/sup&gt;-C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)W(CO)&lt;sub&gt;2&lt;/sub&gt; in THF solution at 0°C indicate that the ring-slipped dicarbonyl complex is catalytically generated by a one-electron oxidation of the tungstenocene monocarbonyl under CO at ambient pressure. Similar results are found for the reaction of (η&lt;sup&gt;5&lt;/sup&gt;-C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;Mo(CO) with CO.</dcterms:abstract>
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    <dcterms:bibliographicCitation>Journal of Organometallic Chemistry ; 365 (1989), 3. - S. 285-295</dcterms:bibliographicCitation>
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