ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling

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1983
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Schwemlein, Heinz
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Journal of Organometallic Chemistry. 1983, 254(1), pp. 69-73. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(83)85118-3
Zusammenfassung

Titanocene and zirconocene derivatives with an interannular tetramethylethylene bridge can be made by reductive coupling of 6,6-dimethylfulvene with sodium amalgam, sodium anthracenide, or magnesium metal/CCl4 as reducing agents and subsequent reaction of the anionic tetramethyldicyclopentadienylethane product with TiCl3 or ZrCl4 in THF.

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ISO 690SCHWEMLEIN, Heinz, Hans-Herbert BRINTZINGER, 1983. ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling. In: Journal of Organometallic Chemistry. 1983, 254(1), pp. 69-73. ISSN 0022-328X. Available under: doi: 10.1016/0022-328X(83)85118-3
BibTex
@article{Schwemlein1983ansaM-23962,
  year={1983},
  doi={10.1016/0022-328X(83)85118-3},
  title={ansa-Metallocene derivatives : V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling},
  number={1},
  volume={254},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={69--73},
  author={Schwemlein, Heinz and Brintzinger, Hans-Herbert}
}
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