ansa-metallocene derivatives : XII. Diastereomeric derivatisation and enantiomer separation of ethylenebis(tetrahydronindenyl)-titanium and -zirconium dichlorides

Schäfer, Andrea; Karl, Eberhard; Zsolnai, Laszlo; Huttner, Gottfried; Brintzinger, Hans-Herbert

ansa-metallocene derivatives : XII. Diastereomeric derivatisation and enantiomer separation of ethylenebis(tetrahydronindenyl)-titanium and -zirconium dichlorides

Dateien

Schaefer_240582.pdfGröße: 578.68 KBDownloads: 342

Datum

1987

Autor:innen

Schäfer, Andrea

Karl, Eberhard

Zsolnai, Laszlo

Huttner, Gottfried

Brintzinger, Hans-Herbert

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Journal of Organometallic Chemistry. 1987, 328(1-2), pp. 87-99. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)99770-5

Zusammenfassung

Derivatisation of racemic ethylene-bridged bis(4,5,6,7tetrahydro-1-indenyl)-titanium and -zirconium dichlorides with O-acetyl-r-mandelic acid affords diastereomers which can be separately crystallised. Crystal and molecular structures of these diastereomers reveal different chelate ring conformations in the crystalline state. The separated diastereomers have been converted, via their dimethyl derivatives, into the corresponding titanocene and zirconocene dichloride enantiomers, the optical purity of these enantiomers has been demonstrated by their reconversion into the acetyl-r-mandelate derivatives.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

SCHÄFER, Andrea, Eberhard KARL, Laszlo ZSOLNAI, Gottfried HUTTNER, Hans-Herbert BRINTZINGER, 1987. ansa-metallocene derivatives : XII. Diastereomeric derivatisation and enantiomer separation of ethylenebis(tetrahydronindenyl)-titanium and -zirconium dichlorides. In: Journal of Organometallic Chemistry. 1987, 328(1-2), pp. 87-99. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)99770-5

BibTex

@article{Schafer1987ansam-24058,
  year={1987},
  doi={10.1016/S0022-328X(00)99770-5},
  title={ansa-metallocene derivatives : XII. Diastereomeric derivatisation and enantiomer separation of ethylenebis(tetrahydronindenyl)-titanium and -zirconium dichlorides},
  number={1-2},
  volume={328},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={87--99},
  author={Schäfer, Andrea and Karl, Eberhard and Zsolnai, Laszlo and Huttner, Gottfried and Brintzinger, Hans-Herbert}
}

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