Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents

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2001
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Forsyth, John
Pereña, José M.
Benavente, Rosario
Pérez, Ernesto
Tritto, Incoronata
Boggioni, Laura
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Macromolecular Chemistry and Physics. 2001, 202(5), pp. 614-620. ISSN 1022-1352. eISSN 1521-3935. Available under: doi: 10.1002/1521-3935(20010301)202:5<614::AID-MACP614>3.0.CO;2-C
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This study involves research on possible relationships between the composition of ethylene/norbornene copolymers and their thermal properties. The copolymers were fully characterised by differential scanning calorimetry (DSC), 13C NMR spectroscopy, Fourier transformation infra-red (FTIR) and Raman spectroscopy. The results of this study show that there is no linear correlation between the amount of norbornene incorporated in copolymers and thermal behaviour when copolymers containing high norbornene content and different microstructures are considered. The latter of which was found to be extremely sensitive to the catalyst used in its preparation.

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ISO 690FORSYTH, John, José M. PEREÑA, Rosario BENAVENTE, Ernesto PÉREZ, Incoronata TRITTO, Laura BOGGIONI, Hans-Herbert BRINTZINGER, 2001. Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents. In: Macromolecular Chemistry and Physics. 2001, 202(5), pp. 614-620. ISSN 1022-1352. eISSN 1521-3935. Available under: doi: 10.1002/1521-3935(20010301)202:5<614::AID-MACP614>3.0.CO;2-C
BibTex
@article{Forsyth2001Influ-24064,
  year={2001},
  doi={10.1002/1521-3935(20010301)202:5<614::AID-MACP614>3.0.CO;2-C},
  title={Influence of the polymer microstructure on the thermal properties of cycloolefin copolymers with high norbornene contents},
  number={5},
  volume={202},
  issn={1022-1352},
  journal={Macromolecular Chemistry and Physics},
  pages={614--620},
  author={Forsyth, John and Pereña, José M. and Benavente, Rosario and Pérez, Ernesto and Tritto, Incoronata and Boggioni, Laura and Brintzinger, Hans-Herbert}
}
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