@article{Speranza2003Stere-7648,
  year={2003},
  doi={10.1002/hlca.200390212},
  title={Stereochemistry of the Conversion of 2-Phenoxyethanol into Phenol and Acetaldehyde by Acetobacterium sp.},
  number={7},
  volume={86},
  issn={0018-019X},
  journal={Helvetica Chimica Acta},
  pages={2629--2636},
  author={Speranza, Giovanna and Müller, Britta and Orlandi, Maximilian and Morelli, Carlo F. and Manitto, Paolo and Schink, Bernhard}
}

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    <dcterms:bibliographicCitation>First publ. in: Helvetica Chimica Acta 86 (2003), 7, pp. 2629-2636</dcterms:bibliographicCitation>
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    <dcterms:abstract xml:lang="eng">The conversion of 2-phenoxyethanol to phenol and acetate by the anaerobic bacterium Acetobacterium sp. strain LuPhet1 proceeds through acetaldehyde with concomitant migration of a H-atom from C(1) to C(2) of the glycolic moiety. Separate feeding experiments with (R)- and (S)-2-phenoxy(1-2H)ethanol, prepared via chemoenzymatic syntheses, indicate that the H-atom involved in the 1,2-shift is the pro-S one of the enantiotopic couple of the alcohol function.</dcterms:abstract>
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    <dc:contributor>Manitto, Paolo</dc:contributor>
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