@article{Groth2006Diast-9721,
  year={2006},
  doi={10.1055/s-2006-947349},
  title={Diastereoselective addition of organocerium(III) reagents derived from 3-substituted propargyl bromides to aldehydes},
  number={12},
  volume={2006},
  issn={0936-5214},
  journal={Synlett},
  pages={1859--1862},
  author={Groth, Ulrich and Kesenheimer, Christian and Neidhöfer, Jürgen}
}

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    <dc:creator>Groth, Ulrich</dc:creator>
    <dc:creator>Neidhöfer, Jürgen</dc:creator>
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    <dcterms:abstract xml:lang="eng">Various cerium allenyl reagents were generated by transmetallation of allenyl Grignard compounds with CeCl3 and sub­sequent conversion into homopropargylic alcohols by addition to various aliphatic and aromatic aldehydes. The α-acetylenic alcohols were obtained with regioselectivities and diastereoselectivities up to 98% de in favor of the threo-diastereomers.</dcterms:abstract>
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    <dcterms:title>Diastereoselective addition of organocerium(III) reagents derived from 3-substituted propargyl bromides to aldehydes</dcterms:title>
    <dc:creator>Kesenheimer, Christian</dc:creator>
    <dcterms:issued>2006</dcterms:issued>
    <dc:contributor>Kesenheimer, Christian</dc:contributor>
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    <dcterms:bibliographicCitation>First publ. in: Synlett 2006, 12, pp. 1859-1862</dcterms:bibliographicCitation>
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