Diastereoselective Ce(III)-catalyzed pinacol couplings of aldehydes

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2001
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Jeske, Mario
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Synlett. 2001(1), pp. 129-131. Available under: doi: 10.1055/s-2001-9692
Zusammenfassung

Aliphatic and aromatic aldehydes were converted into the corresponding pinacoles by using different cerium catalysts. Ce(OtBu)3 proved to be superior over other cerium(III) catalysts. Especially the highly diastereoselective pinacol coupling of sterically non demanding aldehydes such as hexanal is remarkable.

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Fachgebiet (DDC)
540 Chemie
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catalysis, cerium, diastereoselectivity, lanthanides, pinacol coupling
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ISO 690GROTH, Ulrich, Mario JESKE, 2001. Diastereoselective Ce(III)-catalyzed pinacol couplings of aldehydes. In: Synlett. 2001(1), pp. 129-131. Available under: doi: 10.1055/s-2001-9692
BibTex
@article{Groth2001Diast-9545,
  year={2001},
  doi={10.1055/s-2001-9692},
  title={Diastereoselective Ce(III)-catalyzed pinacol couplings of aldehydes},
  number={1},
  journal={Synlett},
  pages={129--131},
  author={Groth, Ulrich and Jeske, Mario}
}
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