@article{Hafner1980Kinet-9535,
  year={1980},
  doi={10.1016/0009-2614(80)85221-3},
  title={Kinetic analysis of the abnormal fluorimetric titration behaviour of naphthylamines},
  number={1},
  volume={73},
  issn={0009-2614},
  journal={Chemical Physics Letters},
  pages={139--144},
  author={Hafner, Friedrich and Wörner, Jörg and Steiner, Ulrich and Hauser, Manfred}
}

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    <dcterms:bibliographicCitation>First publ. in: Chemical Physics Letters 73 (1980), 1, pp. 139-144</dcterms:bibliographicCitation>
    <dc:creator>Wörner, Jörg</dc:creator>
    <dc:contributor>Steiner, Ulrich</dc:contributor>
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    <dc:contributor>Hafner, Friedrich</dc:contributor>
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    <dc:contributor>Wörner, Jörg</dc:contributor>
    <dcterms:abstract xml:lang="eng">The fluorimetric titration behaviour of naphthylamines is abnormal in that the sum of the reduced quantum yields of conjugated acid and base passes through a minimum. Based on fluorescence quantum yield and lifetime measurements, we explain this behaviour by two independent mechanisms: A diabatic quenching of the excited base by protons and a decrease of the excited cation's protolytic dissociation in the hyperacidic region. Though apparently independent processes, their rate constants can be shown to be related to each other by a quasi-thermodynamical equation.</dcterms:abstract>
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    <dc:contributor>Hauser, Manfred</dc:contributor>
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