Asymmetric Synthesis of Enantiomerically Pure Phosphonic Analogues of Glutamic Acid and Proline

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1992
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Richter, Lutz
Schöllkopf, Ulrich
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Tetrahedron. 1992, 48(1), pp. 117-122. ISSN 0040-4020. Available under: doi: 10.1016/S0040-4020(01)80584-6
Zusammenfassung

Michael addition of the metallated camphor derivatives 2 to vinylogous esters and subsequential hydrolysis afforded phosphonic analogues of glutamic acid. The enantiomerically pure lactam 6 was reduced by LiBH4/BF3·OEt2 to phosphoproline 7.

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ISO 690GROTH, Ulrich, Lutz RICHTER, Ulrich SCHÖLLKOPF, 1992. Asymmetric Synthesis of Enantiomerically Pure Phosphonic Analogues of Glutamic Acid and Proline. In: Tetrahedron. 1992, 48(1), pp. 117-122. ISSN 0040-4020. Available under: doi: 10.1016/S0040-4020(01)80584-6
BibTex
@article{Groth1992Asymm-9985,
  year={1992},
  doi={10.1016/S0040-4020(01)80584-6},
  title={Asymmetric Synthesis of Enantiomerically Pure Phosphonic Analogues of Glutamic Acid and Proline},
  number={1},
  volume={48},
  issn={0040-4020},
  journal={Tetrahedron},
  pages={117--122},
  author={Groth, Ulrich and Richter, Lutz and Schöllkopf, Ulrich}
}
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