Magnetic field effect on picosecond electron transfer

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1998
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Gilch, Peter
Pöllinger-Dammer, Florian
Musewald, Christian
Michel-Beyerle, Maria Elisabeth
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Science. 1998, 281(5379), pp. 982-984. Available under: doi: 10.1126/science.281.5379.982
Zusammenfassung

The recombination dynamics of a transition metal redox system monitored by femtosecond pump-probe spectroscopy are shown to be sensitive to high magnetic fields at times shorter than 10 picoseconds. The effect, based on coherent population beats of different spin states, is quantitatively accounted for and allows direct access to spin relaxation rates far beyond the time resolution of the fastest electron paramagnetic resonance technique. The presence of this ultrafast magnetic field effect helps in understanding complex reaction schemes in transition metal chemistry, which occur in a wide range of fields, such as bioinorganic chemistry and catalysis.

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540 Chemie
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ISO 690GILCH, Peter, Florian PĂ–LLINGER-DAMMER, Christian MUSEWALD, Maria Elisabeth MICHEL-BEYERLE, Ulrich STEINER, 1998. Magnetic field effect on picosecond electron transfer. In: Science. 1998, 281(5379), pp. 982-984. Available under: doi: 10.1126/science.281.5379.982
BibTex
@article{Gilch1998Magne-10037,
  year={1998},
  doi={10.1126/science.281.5379.982},
  title={Magnetic field effect on picosecond electron transfer},
  number={5379},
  volume={281},
  journal={Science},
  pages={982--984},
  author={Gilch, Peter and Pöllinger-Dammer, Florian and Musewald, Christian and Michel-Beyerle, Maria Elisabeth and Steiner, Ulrich}
}
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