@article{Ghisla1980Chemi-8425,
  year={1980},
  doi={10.1021/bi00553a001},
  title={Chemical Synthesis and Some Properties of 6-Substituted Flavins},
  number={12},
  volume={19},
  issn={0006-2960},
  journal={Biochemistry},
  pages={2538--2544},
  author={Ghisla, Sandro and Kenney, William C. and Knappe, Wolfgang R. and McIntire, William and Singer, Thomas P.}
}

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    <dcterms:abstract xml:lang="eng">A number of derivatives of riboflavin and of 3-methyllumiflavin substituted in the 6 position have been synthesized starting with 6-nitro flavins, reduction to the 6-amino flavin, and diazotization, followed by reaction with the appropriate nucleophile. The absorption spectra, oxidation-reduction potentials, and the electron spin resonance spectra of the radical cationic forms of several of these synthetic compounds have been determined, including 6-S-cysteinyl-3-methyllumiflavin and 6-S-cysteinylriboflavin. The latter has been shown to be identical with the dephosphorylated form of the aminoacyl flavin isolated from trimethylamine dehydrogenase [Steenkamp, D. J., Kenney, W . C., &amp; Singer, T. P. (1978) J. Biol. Chem. 253, 2812-2817; Steenkamp, D. J., McIntire, W., &amp; Kenney, W. C. (1978) J. Biol. Chem. 253, 2818-2824] in regard to absorption spectrum, photochemical properties, and mobility in high-voltage electrophoresis and in thin-layer chromatography. An unusually pronounced interaction between the amino group and the isoalloxazine ring system was deduced from the absorption spectra of 6-amino-3-methyllumiflavin and 6-aminoriboflavin.</dcterms:abstract>
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    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T17:43:30Z</dc:date>
    <dc:contributor>Ghisla, Sandro</dc:contributor>
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    <dcterms:title>Chemical Synthesis and Some Properties of 6-Substituted Flavins</dcterms:title>
    <dc:contributor>Kenney, William C.</dc:contributor>
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    <dc:contributor>Singer, Thomas P.</dc:contributor>
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    <dc:creator>Ghisla, Sandro</dc:creator>
    <dc:creator>McIntire, William</dc:creator>
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    <dcterms:issued>1980</dcterms:issued>
    <dc:contributor>McIntire, William</dc:contributor>
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    <dcterms:bibliographicCitation>First publ. in: Biochemistry 19 (1980), 12, pp. 2538-2544</dcterms:bibliographicCitation>
    <dc:creator>Kenney, William C.</dc:creator>
    <dc:creator>Knappe, Wolfgang R.</dc:creator>
    <dc:creator>Singer, Thomas P.</dc:creator>
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