Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration

Schwab, Ernst; Mecking, Stefan

Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration

Dateien

2001_Organometallics_20_5504_Mecking_Schwab.pdfGröße: 55.6 KBDownloads: 485

Datum

2001

Autor:innen

Schwab, Ernst

Mecking, Stefan

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Organometallics. 2001, 20(26), pp. 5504-5506. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om0107542

Zusammenfassung

Binding via noncovalent electrostatic interactions of multiply sulfonated phosphine ligands with a soluble polyelectrolyte represents a convenient approach for immobilization of a catalytically active rhodium complex. As a polyelectrolyte, PDADMA-BArF 4 (poly-(diallyldimethylammonium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate)) can be utilized. The polyelectrolyte-bound catalyst is active for hexene hydroformylation, and it can be recovered and recycled by ultrafiltration.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

SCHWAB, Ernst, Stefan MECKING, 2001. Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration. In: Organometallics. 2001, 20(26), pp. 5504-5506. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om0107542

BibTex

@article{Schwab2001Immob-9810,
  year={2001},
  doi={10.1021/om0107542},
  title={Immobilization of a catalytically active rhodium complex by electrostatic interactions of multiply charged phosphine ligands with a soluble polyelectrolyte and recovery by ultrafiltration},
  number={26},
  volume={20},
  issn={0276-7333},
  journal={Organometallics},
  pages={5504--5506},
  author={Schwab, Ernst and Mecking, Stefan}
}

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