@article{Steiner1981Heavy-9575,
  year={1981},
  doi={10.1007/BF02721449},
  title={Heavy Atoms as Molecular Probes in Studying the Solvent Dependence of the Dynamics of Triplet Exciplexes},
  number={1},
  volume={63 B},
  journal={Il Nuovo Cimento},
  pages={431--440},
  author={Steiner, Ulrich and Winter, Gerhard}
}

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    <dc:creator>Winter, Gerhard</dc:creator>
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    <dc:contributor>Winter, Gerhard</dc:contributor>
    <dcterms:title>Heavy Atoms as Molecular Probes in Studying the Solvent Dependence of the Dynamics of Triplet Exciplexes</dcterms:title>
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    <dcterms:bibliographicCitation>First publ. in: Il Nuovo Cimento 63 B (1981), 1, pp. 431-440</dcterms:bibliographicCitation>
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    <dc:contributor>Steiner, Ulrich</dc:contributor>
    <dcterms:abstract xml:lang="eng">Electron transfer reactions between thiopyronine triplet (acceptor 3A+) and the electron donors (D), aniline, p-Br-aniline and p-I-aniline, are investigated by flash spectroscopy in solvents of different viscosity and polarity. Due to the heavy-atom effect the radical yield becomes very sensitive to the solvent influence, which can be explained by the dynamic properties of a triplet exciplex (3(AD+)) formed as a primary product in the reaction between acceptor triplet and donor. Whereas on variation of solvent viscosity the solvent cage effect on the dissociation of 3(AD+) is observed, a change in solvent polarity is suggested to affect the radiationless deactivation of 3(AD+) to the ground state of the components.</dcterms:abstract>
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