One-dimensional (Mo3S3)n clusters : building blocks of clusters materials and ideal nanowires for molecular electronics

Gemming, Sibylle; Seifert, Gotthard; Bertram, Nils; Fischer, Tim; Götz, Matthias; Ganteför, Gerd

One-dimensional (Mo3S3)n clusters : building blocks of clusters materials and ideal nanowires for molecular electronics

Dateien

ChemPhysLett474.pdfGröße: 417.34 KBDownloads: 253

Datum

2009

Autor:innen

Gemming, Sibylle

Seifert, Gotthard

Bertram, Nils

Fischer, Tim

Götz, Matthias

Ganteför, Gerd

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Physik

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Chemical Physics Letters. 2009, 474(1-3), pp. 127-131. Available under: doi: 10.1016/j.cplett.2009.04.020

Zusammenfassung

The geometric and electronic structures of gas phase (Mo3S3)nS2 and (Mo3S3)n-1(MoS4)2 clusters with n = 2, 3, 4, . . . are studied experimentally using mass and photoelectron spectroscopy. The Mo3S3 units form one-dimensional chains with length n . There are two possible types of terminations at the ends: a single S atom or a MoS4 cluster. The experimental results are compared to calculations based on density- functional theory. Although clusters of this type have been known for decades as constituents of Chevrel phases, we here report their first gas phase synthesis for sizes up to n = 17. With increasing n, the gap vanishes extending such clusters to a conducting wire.

Fachgebiet (DDC)

530 Physik

Zitieren

ISO 690

GEMMING, Sibylle, Gotthard SEIFERT, Nils BERTRAM, Tim FISCHER, Matthias GÖTZ, Gerd GANTEFÖR, 2009. One-dimensional (Mo3S3)n clusters : building blocks of clusters materials and ideal nanowires for molecular electronics. In: Chemical Physics Letters. 2009, 474(1-3), pp. 127-131. Available under: doi: 10.1016/j.cplett.2009.04.020

BibTex

@article{Gemming2009Onedi-5322,
  year={2009},
  doi={10.1016/j.cplett.2009.04.020},
  title={One-dimensional (Mo3S3)n clusters : building blocks of clusters materials and ideal nanowires for molecular electronics},
  number={1-3},
  volume={474},
  journal={Chemical Physics Letters},
  pages={127--131},
  author={Gemming, Sibylle and Seifert, Gotthard and Bertram, Nils and Fischer, Tim and Götz, Matthias and Ganteför, Gerd}
}

RDF

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/5322">
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/5322/1/ChemPhysLett474.pdf"/>
    <dc:creator>Ganteför, Gerd</dc:creator>
    <dc:rights>terms-of-use</dc:rights>
    <dc:contributor>Gemming, Sibylle</dc:contributor>
    <dc:contributor>Fischer, Tim</dc:contributor>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dc:contributor>Seifert, Gotthard</dc:contributor>
    <dc:language>deu</dc:language>
    <dc:contributor>Götz, Matthias</dc:contributor>
    <dcterms:bibliographicCitation>First publ. in: Chemical Physics Letters 474 (2009), 1-3, pp. 127 131</dcterms:bibliographicCitation>
    <dc:contributor>Ganteför, Gerd</dc:contributor>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/41"/>
    <dc:contributor>Bertram, Nils</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:54:55Z</dcterms:available>
    <dc:creator>Fischer, Tim</dc:creator>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/5322/1/ChemPhysLett474.pdf"/>
    <dc:creator>Götz, Matthias</dc:creator>
    <dcterms:abstract xml:lang="eng">The geometric and electronic structures of gas phase (Mo3S3)nS2 and (Mo3S3)n-1(MoS4)2 clusters with n = 2, 3, 4, . . . are studied experimentally using mass and photoelectron spectroscopy. The Mo3S3 units form one-dimensional chains with length  n . There are two possible types of terminations at the ends: a single S atom or a MoS4 cluster. The experimental results are compared to calculations based on density- functional theory. Although clusters of this type have been known for decades as constituents of Chevrel phases, we here report their first gas phase synthesis for sizes up to n = 17. With increasing n, the gap vanishes extending such clusters to a conducting wire.</dcterms:abstract>
    <dc:format>application/pdf</dc:format>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T14:54:55Z</dc:date>
    <dc:creator>Gemming, Sibylle</dc:creator>
    <dc:creator>Seifert, Gotthard</dc:creator>
    <dc:creator>Bertram, Nils</dc:creator>
    <dcterms:title>One-dimensional (Mo3S3)n clusters : building blocks of clusters materials and ideal nanowires for molecular electronics</dcterms:title>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/5322"/>
    <dcterms:issued>2009</dcterms:issued>
  </rdf:Description>
</rdf:RDF>

Universitätsbibliographie

Ja