Electronic structure of small fullerenes : evidence for the high stability of C32

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PhysRevLett81199824.pdf
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1998
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Kietzmann, Hardy
Rochow, Regina
Eberhardt, Wolfgang
Vietze, Knut
Seifert, Gotthard
Fowler, Patrick W.
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Physical Review Letters. 1998, 81(24), pp. 5378-5381. Available under: doi: 10.1103/PhysRevLett.81.5378
Zusammenfassung

The electronic structure of small fullerenes determined experimentally by anion photoelectron spectroscopy is compared with calculations. A huge mass signal and a large gap of 1.3 eV comparable to the gap of C70 have been found for C32, indicating that this cluster is the most stable fullerene below C60. Also C36, C44, and C50 exhibit large gaps and surprisingly high stabilities. The criteria for the selection of clusters sufficiently stable to form a cluster material are discussed.

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ISO 690KIETZMANN, Hardy, Regina ROCHOW, Gerd GANTEFĂ–R, Wolfgang EBERHARDT, Knut VIETZE, Gotthard SEIFERT, Patrick W. FOWLER, 1998. Electronic structure of small fullerenes : evidence for the high stability of C32. In: Physical Review Letters. 1998, 81(24), pp. 5378-5381. Available under: doi: 10.1103/PhysRevLett.81.5378
BibTex
@article{Kietzmann1998Elect-4704,
  year={1998},
  doi={10.1103/PhysRevLett.81.5378},
  title={Electronic structure of small fullerenes : evidence for the high stability of C32},
  number={24},
  volume={81},
  journal={Physical Review Letters},
  pages={5378--5381},
  author={Kietzmann, Hardy and Rochow, Regina and Ganteför, Gerd and Eberhardt, Wolfgang and Vietze, Knut and Seifert, Gotthard and Fowler, Patrick W.}
}
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