Universität zu Köln

Busch, Stefanie, Stein, Irena and Ruschewitz, Uwe ORCID: 0000-0002-6511-6894 (2012). Hydrate Isomerism in Coordination Polymers of Bismuth and Acetylenedicarboxylate. Z. Anorg. Allg. Chem., 638 (12-13). S. 2098 - 2102. WEINHEIM: WILEY-V C H VERLAG GMBH. ISSN 1521-3749

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Abstract

Single crystals of (2)(infinity)[Bi(ADC)(2/4)(ADC)(3/3)(H2O)2]center dot 2H(2)O (P (1) over bar$\bar, Z = 2) and (3)(infinity)[Bi(ADC)(2/4)(ADC)(3/3)(H2O)(3)]center dot H2O (P (1) over bar, Z = 2) were obtained by isothermal evaporation of aqueous solutions containing acetylenedicarboxylic acid (H(2)ADC) and Bi(NO3)(3)center dot 5H(2)O. Their crystal structures were solved and refined from X-ray single crystal data. They are hydrate isomers with respect to the central Bi3+ ion, which leads to completely different topologies of the resulting coordination polymers.

Item Type:	Journal Article
Creators:	Creators Email ORCID ORCID Put Code Busch, Stefanie UNSPECIFIED UNSPECIFIED UNSPECIFIED Stein, Irena UNSPECIFIED UNSPECIFIED UNSPECIFIED Ruschewitz, Uwe UNSPECIFIED orcid.org/0000-0002-6511-6894 UNSPECIFIED
URN:	urn:nbn:de:hbz:38-481457
DOI:	10.1002/zaac.201200006
Journal or Publication Title:	Z. Anorg. Allg. Chem.
Volume:	638
Number:	12-13
Page Range:	S. 2098 - 2102
Date:	2012
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	WEINHEIM
ISSN:	1521-3749
Language:	English
Faculty:	Unspecified
Divisions:	Unspecified
Subjects:	no entry
Uncontrolled Keywords:	Keywords Language METAL-ORGANIC FRAMEWORKS; INDUSTRIAL APPLICATIONS; ANHYDROUS SALT; ACID; DIANION; COMPLEX Multiple languages Chemistry, Inorganic & Nuclear Multiple languages
URI:	http://kups.ub.uni-koeln.de/id/eprint/48145