Seidel, Christiane, Ahlers, Ruth and Ruschewitz, Uwe ORCID: 0000-0002-6511-6894 (2011). Coordination Polymers with Tetrafluoroterephthalate as Bridging Ligand. Cryst. Growth Des., 11 (11). S. 5053 - 5064. WASHINGTON: AMER CHEMICAL SOC. ISSN 1528-7483

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Abstract

Seven nonporous coordination polymers with tetrafluoroterephthalate (tfBDC(2-)) as a bridging ligand were synthesized and structurally characterized. Homoleptic (3)(infinity) [Tl-2 (tfBDC)] (p (1) over bar, Z = 1, 1) contains six-coordinated Tl centers, which are connected by the tfflDC(2-) ligand to form a three-dimenSional (3D) network. Upon heating it decomposes at approximately 200 degrees C. Nine-coordinated PbO9 polyhedra are found in (2) (infinity)[Pb(tfBDC)(H2O)(3)]center dot 1/2 H2O (P (1) over bar, Z = 1, 2), which forms a layer-like structure. These layers are held together by hydrogen bonds involving water molecules. These water molecules are released by heating to 70-100 degrees C. (1)(infinity)[M-II(tfBDC)(H2O)(4)] (P (1) over bar, Z = 1; M-II = Zn (3), Co (4), Ni (5)) contains almost undistorted MI106 octahedra with the carboxylate groups of the tfBDC ligands in trans coordination so that a chain-like structural unit is formed. These chains are further connected by hydrogen bonds. Upon heating, these water molecules are released in two steps at 100 and 200 degrees C. (3)(infinity) [Mn-2(tfBDC)(2)(DMF)(2)(EtOH)] (P2(1), Z = 2, 7) is isostructural to the known Zn compound (6). Both compounds contain dimeric [(MO6)-O-II](2) units, which are connected by tfBDC(2-) ligands to form a 3D network. All compounds are unprecedented in the crystal chemistry of coordination polymers with nonfluorinated terephthalate (BDC2-) as bridging ligand. This is mainly because the planar conformation found for BDC2- is energetically less favorable for perfluorinated tfBDC(2-).

Item Type: Journal Article
Creators:
CreatorsEmailORCIDORCID Put Code
Seidel, ChristianeUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Ahlers, RuthUNSPECIFIEDUNSPECIFIEDUNSPECIFIED
Ruschewitz, UweUNSPECIFIEDorcid.org/0000-0002-6511-6894UNSPECIFIED
URN: urn:nbn:de:hbz:38-486283
DOI: 10.1021/cg200974h
Journal or Publication Title: Cryst. Growth Des.
Volume: 11
Number: 11
Page Range: S. 5053 - 5064
Date: 2011
Publisher: AMER CHEMICAL SOC
Place of Publication: WASHINGTON
ISSN: 1528-7483
Language: English
Faculty: Unspecified
Divisions: Unspecified
Subjects: no entry
Uncontrolled Keywords:
KeywordsLanguage
METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; CRYSTAL-STRUCTURE; INDUSTRIAL APPLICATIONS; ADSORPTION SITES; GAS-ADSORPTION; DESIGN; ACID; APPROXIMATION; BEHAVIORMultiple languages
Chemistry, Multidisciplinary; Crystallography; Materials Science, MultidisciplinaryMultiple languages
URI: http://kups.ub.uni-koeln.de/id/eprint/48628

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