- AutorIn
- Diplom-Physiker Sven Welack
- Titel
- Reduced Density Matrix Approach to the Laser-Assisted Electron Transport in Molecular Wires
- Zitierfähige Url:
- https://nbn-resolving.org/urn:nbn:de:swb:ch1-200600571
- Datum der Einreichung
- 30.11.2005
- Abstract (EN)
- The electron transport through a molecular wire under the influence of an external laser field is studied using a reduced density matrix formalism. The full system is partitioned into the relevant part, i.e. the wire, electron reservoirs and a phonon bath. An earlier second-order perturbation theory approach of Meier and Tannor for bosonic environments which employs a numerical decomposition of the spectral density is used to describe the coupling to the phonon bath and is extended to deal with the electron transfer between the reservoirs and the molecular wire. Furthermore, from the resulting time-nonlocal (TNL) scheme a time-local (TL) approach can be determined. Both are employed to propagate the reduced density operator in time for an arbitrary time-dependent system Hamiltonian which incorporates the laser field non-perturbatively. Within the TL formulation, one can extract a current operator for the open quantum system. This enables a more general formulation of the problem which is necessary to employ an optimal control algorithm for open quantum systems in order to compute optimal control fields for time-distributed target states, e.g. current patterns. Thus, we take a fundamental step towards optimal control in molecular electronics. Numerical examples of the population dynamics, laser controlled current, TNL vs. TL and optimal control fields are presented to demonstrate the diverse applicability of the derived formalism.
- Freie Schlagwörter
- electron transport
- molecular wires
- non-Markovian
- reduced density matrix
- time-dependent transport
- Klassifikation (DDC)
- 530
- Normschlagwörter (GND)
- Dichtematrix
- Elektronentransport
- Quantenmechanik
- Den akademischen Grad verleihende / prüfende Institution
- Technische Universität Chemnitz, Chemnitz
- Förder- / Projektangaben
- URN Qucosa
- urn:nbn:de:swb:ch1-200600571
- Veröffentlichungsdatum Qucosa
- 07.04.2006
- Dokumenttyp
- Diplomarbeit
- Sprache des Dokumentes
- Englisch