Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives

Ghadwal, Rajendra; Rottschäfer, Dennis; Glodde, Timo; Neumann, Beate; Stammler, Hans-Georg; Andrada, Diego

Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives

Ghadwal R, Rottschäfer D, Glodde T, Neumann B, Stammler H-G, Andrada D (Accepted)
Angewandte Chemie International Edition .

Zeitschriftenaufsatz | Angenommen | Englisch

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Angew Chem Int Ed - 2021 - Rottsch fer - Isolation of 1 4_u2010Diarsinine_u20101 4_u2010diide and 1 4_u2010Diarsinine Derivatives.pdf 1.70 MB

DOI

https://doi.org/10.1002/anie.202105835

URN

urn:nbn:de:0070-pub-29552474

Autor*in

Ghadwal, Rajendra^UniBi ; Rottschäfer, Dennis^UniBi; Glodde, Timo^UniBi; Neumann, Beate^UniBi; Stammler, Hans-Georg^UniBi; Andrada, Diego

Einrichtung

Fakultät für Chemie > Anorganische Chemie und Strukturchemie

Abstract / Bemerkung

1,4-Diarsinine-1,4-diide compound [(ADC Ph )As] 2 ( 5 ) (ADC Ph = {C(DippN)} 2 CPh, Dipp = 2,6- i Pr 2 C 6 H 3 ) with a planar C 4 As 2 -ring fused between two 1,3-imidazole scaffolds has been isolated as a red crystalline solid. Compound 5 , formally comprising an 8pi-electron C 4 As 2 -ring, is antiaromatic and undergoes 2e-oxidation with AgOTf to form the 6pi-electron aromatic system [(ADC Ph )As] 2 (OTf) 2 ( 6 ). © 2021 Wiley-VCH GmbH.

Erscheinungsjahr

2021

Zeitschriftentitel

Angewandte Chemie International Edition

Urheberrecht / Lizenzen

Creative Commons Namensnennung - Nicht kommerziell - Keine Bearbeitungen 4.0 International (CC BY-NC-ND 4.0)

eISSN

1521-3773

Finanzierungs-Informationen

Open-Access-Publikationskosten wurden durch die Universität Bielefeld im Rahmen des DEAL-Vertrags gefördert.

Page URI

https://pub.uni-bielefeld.de/record/2955247

Zitieren

Ghadwal R, Rottschäfer D, Glodde T, Neumann B, Stammler H-G, Andrada D. Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition . Accepted.

Ghadwal, R., Rottschäfer, D., Glodde, T., Neumann, B., Stammler, H. - G., & Andrada, D. (Accepted). Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition . https://doi.org/10.1002/anie.202105835

Ghadwal, Rajendra, Rottschäfer, Dennis, Glodde, Timo, Neumann, Beate, Stammler, Hans-Georg, and Andrada, Diego. Accepted. “Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives”. Angewandte Chemie International Edition .

Ghadwal, R., Rottschäfer, D., Glodde, T., Neumann, B., Stammler, H. - G., and Andrada, D. (Accepted). Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition .

Ghadwal, R., et al., Accepted. Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition .

R. Ghadwal, et al., “Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives”, Angewandte Chemie International Edition , Accepted.

Ghadwal, R., Rottschäfer, D., Glodde, T., Neumann, B., Stammler, H.-G., Andrada, D.: Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives. Angewandte Chemie International Edition . (Accepted).

Ghadwal, Rajendra, Rottschäfer, Dennis, Glodde, Timo, Neumann, Beate, Stammler, Hans-Georg, and Andrada, Diego. “Isolation of 1,4-Diarsinine-1,4-diide and 1,4-Diarsinine Derivatives”. Angewandte Chemie International Edition (Accepted).

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