An electrically actuated molecular toggle switch
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Molecular electronics is considered a promising approach for future nanoelectronic devices. In order that molecular junctions can be used as electrical switches or even memory devices, they need to be actuated between two distinct conductance states in a controlled and reproducible manner by external stimuli. Here we present a tripodal platform with a cantilever arm and a nitrile group at its end that is lifted from the surface. The formation of a coordinative bond between the nitrile nitrogen and the gold tip of a scanning tunnelling microscope can be controlled by both electrical and mechanical means, and leads to a hysteretic switching of the conductance of the junction by more than two orders of magnitude. This toggle switch can be actuated with high reproducibility so that the forces involved in the mechanical deformation of the molecular cantilever can be determined precisely with scanning tunnelling microscopy.
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GERHARD, Lukas, Kevin EDELMANN, Jan HOMBERG, Michal VALÁŠEK, Safa G. BAHOOSH, Maya LUKAS, Fabian PAULY, Marcel MAYOR, Wulf WULFHEKEL, 2017. An electrically actuated molecular toggle switch. In: Nature Communications. 2017, 8, 14672. eISSN 2041-1723. Available under: doi: 10.1038/ncomms14672BibTex
@article{Gerhard2017-03-09elect-38651, year={2017}, doi={10.1038/ncomms14672}, title={An electrically actuated molecular toggle switch}, volume={8}, journal={Nature Communications}, author={Gerhard, Lukas and Edelmann, Kevin and Homberg, Jan and Valášek, Michal and Bahoosh, Safa G. and Lukas, Maya and Pauly, Fabian and Mayor, Marcel and Wulfhekel, Wulf}, note={Article Number: 14672} }
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