Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule

Lade...
Vorschaubild
Dateien
Scheer.pdf
Scheer.pdfGröße: 101.12 KBDownloads: 845
Datum
2007
Autor:innen
Scheer, Manfred
Schindler, Andrea
Merkle, Roger
Johnson, Brian P.
Anson, Christopher E.
Virovets, Alexander V.
Herausgeber:innen
Kontakt
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
DOI (zitierfähiger Link)
ArXiv-ID
Internationale Patentnummer
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Green
Sammlungen
Core Facility der Universität Konstanz
Gesperrt bis
Titel in einer weiteren Sprache
Forschungsvorhaben
Organisationseinheiten
Zeitschriftenheft
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Journal of the American Chemical Society. 2007, 129(44), pp. 13386-13387. ISSN 0002-7863. Available under: doi: 10.1021/ja075926m
Zusammenfassung

C60[Cu26Cl26L2{Cp*Fe(η5-P5)}13(CH3CN)9] (L = H2O) represents a first example of a complete encapsulation of C60 itself by an inorganic fullerene-like system via molecular recognition of the five- and sixfold-symmetric structural motif of C60. The product exhibits an inorganic cover consisting of 99 inorganic core atoms from pentaphosphaferrocene and Cu(I) chloride building blocks. This is the first instance of a hollow structure that completely encapsulates C60. The overall spherical molecule possesses an outer diameter of 2.3 nm and shows a remarkable electronic interaction between C60 and the encapsulating giant molecule.

Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690SCHEER, Manfred, Andrea SCHINDLER, Roger MERKLE, Brian P. JOHNSON, Michael LINSEIS, Rainer F. WINTER, Christopher E. ANSON, Alexander V. VIROVETS, 2007. Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule. In: Journal of the American Chemical Society. 2007, 129(44), pp. 13386-13387. ISSN 0002-7863. Available under: doi: 10.1021/ja075926m
BibTex
@article{Scheer2007-11-07Fulle-13798,
  year={2007},
  doi={10.1021/ja075926m},
  title={Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule},
  number={44},
  volume={129},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={13386--13387},
  author={Scheer, Manfred and Schindler, Andrea and Merkle, Roger and Johnson, Brian P. and Linseis, Michael and Winter, Rainer F. and Anson, Christopher E. and Virovets, Alexander V.}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/13798">
    <dc:contributor>Schindler, Andrea</dc:contributor>
    <dc:creator>Virovets, Alexander V.</dc:creator>
    <dc:contributor>Anson, Christopher E.</dc:contributor>
    <dc:contributor>Winter, Rainer F.</dc:contributor>
    <dc:contributor>Merkle, Roger</dc:contributor>
    <dc:contributor>Johnson, Brian P.</dc:contributor>
    <dc:creator>Schindler, Andrea</dc:creator>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dc:contributor>Linseis, Michael</dc:contributor>
    <dc:contributor>Scheer, Manfred</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-22T09:16:47Z</dc:date>
    <dcterms:bibliographicCitation>First publ. in: Journal of the American Chemical Society 129 (2007), 44, pp. 13386–13387</dcterms:bibliographicCitation>
    <dcterms:abstract xml:lang="eng">C60[Cu26Cl26L2{Cp*Fe(η5-P5)}13(CH3CN)9] (L = H2O) represents a first example of a complete encapsulation of C60 itself by an inorganic fullerene-like system via molecular recognition of the five- and sixfold-symmetric structural motif of C60. The product exhibits an inorganic cover consisting of 99 inorganic core atoms from pentaphosphaferrocene and Cu(I) chloride building blocks. This is the first instance of a hollow structure that completely encapsulates C60. The overall spherical molecule possesses an outer diameter of 2.3 nm and shows a remarkable electronic interaction between C60 and the encapsulating giant molecule.</dcterms:abstract>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-06-22T09:16:47Z</dcterms:available>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:creator>Anson, Christopher E.</dc:creator>
    <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/13798"/>
    <dc:creator>Linseis, Michael</dc:creator>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/13798/1/Scheer.pdf"/>
    <dc:rights>terms-of-use</dc:rights>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/13798/1/Scheer.pdf"/>
    <dc:creator>Winter, Rainer F.</dc:creator>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:creator>Merkle, Roger</dc:creator>
    <dc:language>eng</dc:language>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dcterms:title>Fullerene C60 as an Endohedral Molecule within an Inorganic Supramolecule</dcterms:title>
    <dc:creator>Johnson, Brian P.</dc:creator>
    <dc:creator>Scheer, Manfred</dc:creator>
    <dc:contributor>Virovets, Alexander V.</dc:contributor>
    <dcterms:issued>2007-11-07</dcterms:issued>
  </rdf:Description>
</rdf:RDF>
Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Kontakt
URL der Originalveröffentl.
Prüfdatum der URL
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Nein
Begutachtet
Diese Publikation teilen