Improvement of (bipy)Pt(XR)2 (X = O, S) type photosensitizers by covalent dye attachment

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2011
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Zabel, Manfred
Rausch, Andreas
Yersin, Hartmut
Tuczek, Felix
Zális, Stanislav
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Chemical Communications. 2011, 47(22), pp. 6302-6304. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C0CC04443A
Zusammenfassung

Irradiation into the dye-based absorption band of complexes (tBu2bipy)Pt(SR)2 and (tBu2bipy)Pt(OR)2 where R denotes a coumarine-based thiolate and alkoxolate substituent populates the same excited triplet state as is obtained by excitation into the much weaker (RX)2Pt→tBu2bipy (X = O, S) charge-transfer band. This paves the way toward more efficient photosensitizers.

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540 Chemie
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ISO 690PEVNY, Florian, Manfred ZABEL, Rainer F. WINTER, Andreas RAUSCH, Hartmut YERSIN, Felix TUCZEK, Stanislav ZÁLIS, 2011. Improvement of (bipy)Pt(XR)2 (X = O, S) type photosensitizers by covalent dye attachment. In: Chemical Communications. 2011, 47(22), pp. 6302-6304. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/C0CC04443A
BibTex
@article{Pevny2011-06-14Impro-13821,
  year={2011},
  doi={10.1039/C0CC04443A},
  title={Improvement of (bipy)Pt(XR)2 (X = O, S) type photosensitizers by covalent dye attachment},
  number={22},
  volume={47},
  issn={1359-7345},
  journal={Chemical Communications},
  pages={6302--6304},
  author={Pevny, Florian and Zabel, Manfred and Winter, Rainer F. and Rausch, Andreas and Yersin, Hartmut and Tuczek, Felix and Zális, Stanislav}
}
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