Influence of defect type on hydrogen passivation efficacy in multicrystalline silicon solar cells
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We examine the effectiveness of hydrogen passivation as a function of defect type and microstructure at grain boundaries (GBs) in multicrystalline silicon. We analyze a solar cell with alternating mm-wide bare and SiNx-coated stripes using laser-beam-induced current, electron backscatter diffraction, X-ray fluorescence microscopy, and defect etching to correlate pre- and post-hydrogenation recombination activity with GB character, density of iron-silicide nanoprecipitates, and dislocations. A strong correlation was found between GB recombination activity and the nature/density of etch pits along the boundaries, while iron silicide precipitates above detection limits were found to play a less significant role.
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BERTONI, Mariana, Steve HUDELSON, Bonna NEWMAN, David FENNING, Harold F.W. DEKKERS, Emanuele CORNAGLIOTTI, Annika ZUSCHLAG, Gabriel MICARD, Giso HAHN, Gianluca COLETTI, Barry LAI, Tonio BUONASSISI, 2011. Influence of defect type on hydrogen passivation efficacy in multicrystalline silicon solar cells. In: Progress in Photovoltaics: Research and Applications. 2011, 19(2), pp. 187-191. ISSN 1062-7995. Available under: doi: 10.1002/pip.1008BibTex
@article{Bertoni2011Influ-15508, year={2011}, doi={10.1002/pip.1008}, title={Influence of defect type on hydrogen passivation efficacy in multicrystalline silicon solar cells}, number={2}, volume={19}, issn={1062-7995}, journal={Progress in Photovoltaics: Research and Applications}, pages={187--191}, author={Bertoni, Mariana and Hudelson, Steve and Newman, Bonna and Fenning, David and Dekkers, Harold F.W. and Cornagliotti, Emanuele and Zuschlag, Annika and Micard, Gabriel and Hahn, Giso and Coletti, Gianluca and Lai, Barry and Buonassisi, Tonio} }
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