Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures

Cölfen, Helmut; Mann, Stephan

Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures

Dateien

Coelfen_166421.pdfGröße: 1.4 MBDownloads: 3818

Datum

2003

Autor:innen

Cölfen, Helmut

Mann, Stephan

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Angewandte Chemie International Edition. 2003, 42(21), pp. 2350-2365. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200200562

Zusammenfassung

The organization of nanostructures across extended length scales is a key challenge in the design of integrated materials with advanced functions. Current approaches tend to be based on physical methods, such as patterning,rather than the spontaneous chemical assembly and transformation of building blocks across multiple length scales. It should be possible to develop a chemistry of organized matter based on emergent processes in which time- and scale-dependent coupling of interactive components generate higher-order architectures with embedded structure. Herein we highlight how the interplay between aggregation and crystallization can give rise to mesoscale selfassembly and cooperative transformation and reorganization of hybrid inorganic–organic building blocks to produce single-crystal mosaics,nanoparticle arrays,and emergent nanostructures with complex form and hierarchy. We propose that similar mesoscale processes are also relevant to models of matrix-mediated nucleation in biomineralization.

Fachgebiet (DDC)

540 Chemie

Schlagwörter

biomineralization, crystal growth, materials science, self-assembly, solid-state chemistry

Zitieren

ISO 690

CÖLFEN, Helmut, Stephan MANN, 2003. Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures. In: Angewandte Chemie International Edition. 2003, 42(21), pp. 2350-2365. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200200562

BibTex

@article{Colfen2003-05-30Highe-16642,
  year={2003},
  doi={10.1002/anie.200200562},
  title={Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures},
  number={21},
  volume={42},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={2350--2365},
  author={Cölfen, Helmut and Mann, Stephan}
}

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