Controlled Cobalt-Mediated Free-Radical Co- and Terpolymerization of Carbon Monoxide

Fuchs, Amelie S.; Mecking, Stefan

Controlled Cobalt-Mediated Free-Radical Co- and Terpolymerization of Carbon Monoxide

Dateien

Fuchs_2-9rnbbep4lw1c8.pdfGröße: 196.85 KBDownloads: 16

Datum

2022

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Chemie

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Journal of the American Chemical Society. American Chemical Society. 2022, 144(34), pp. 15879-15884. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.2c07200

Zusammenfassung

While controlled free-radical polymerizations are established for a vast range of vinyl monomers, they have not been reported for carbon monoxide, although it is a unique monomer that forms in-chain keto groups which can promote, for example, desirable photo-degradability in polyethylenes. We report organometallic-mediated radical copolymerization of carbon monoxide with ethylene initiated by an organocobaltIII compound to keto-modified polyethylenes with up to 15 mol % ketone repeat units. Terpolymerization with 2-methylene-1,3-dioxepane affords polyethylenes with in-chain ester and keto groups. Compared to ethylene homopolymerization, the controlled character of the copolymerization is strongly enhanced by the Lewis base function of carbon monoxide, which suppresses multiple unfavorable termination pathways.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

FUCHS, Amelie S., Stefan MECKING, 2022. Controlled Cobalt-Mediated Free-Radical Co- and Terpolymerization of Carbon Monoxide. In: Journal of the American Chemical Society. American Chemical Society. 2022, 144(34), pp. 15879-15884. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/jacs.2c07200

BibTex

@article{Fuchs2022-08-31Contr-58333,
  year={2022},
  doi={10.1021/jacs.2c07200},
  title={Controlled Cobalt-Mediated Free-Radical Co- and Terpolymerization of Carbon Monoxide},
  number={34},
  volume={144},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={15879--15884},
  author={Fuchs, Amelie S. and Mecking, Stefan}
}

RDF

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/58333">
    <dcterms:issued>2022-08-31</dcterms:issued>
    <dc:creator>Fuchs, Amelie S.</dc:creator>
    <dcterms:abstract xml:lang="eng">While controlled free-radical polymerizations are established for a vast range of vinyl monomers, they have not been reported for carbon monoxide, although it is a unique monomer that forms in-chain keto groups which can promote, for example, desirable photo-degradability in polyethylenes. We report organometallic-mediated radical copolymerization of carbon monoxide with ethylene initiated by an organocobaltIII compound to keto-modified polyethylenes with up to 15 mol % ketone repeat units. Terpolymerization with 2-methylene-1,3-dioxepane affords polyethylenes with in-chain ester and keto groups. Compared to ethylene homopolymerization, the controlled character of the copolymerization is strongly enhanced by the Lewis base function of carbon monoxide, which suppresses multiple unfavorable termination pathways.</dcterms:abstract>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:title>Controlled Cobalt-Mediated Free-Radical Co- and Terpolymerization of Carbon Monoxide</dcterms:title>
    <dc:language>eng</dc:language>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-08-18T13:55:44Z</dc:date>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/58333/1/Fuchs_2-9rnbbep4lw1c8.pdf"/>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/58333"/>
    <dc:creator>Mecking, Stefan</dc:creator>
    <dc:contributor>Fuchs, Amelie S.</dc:contributor>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <dc:rights>terms-of-use</dc:rights>
    <dc:contributor>Mecking, Stefan</dc:contributor>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2022-08-18T13:55:44Z</dcterms:available>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/58333/1/Fuchs_2-9rnbbep4lw1c8.pdf"/>
  </rdf:Description>
</rdf:RDF>

Universitätsbibliographie

Ja

Begutachtet

Ja